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Synthesis of Hydrazine Derivatives

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Cu-catalyzed and metal-free conditions developed for allyltrimethoxysilane addition to N-benzoylhydrazones enable efficient and versatile access to homoallylic α-branched amines. Aldehyde hydrazones, both aromatic and aliphatic, and ketone hydrazones all give good yields.
H. Ding, G. K. Friestadt, Synthesis, 2004, 2216-2221.