Categories: C-H Bond Formation >
Desilylations
Recent Literature
A procedure for protiodesilylation of 1-(trimethylsilyl)-1-alkynes involves
the use of catalytic amounts of AgNO3. The mechanism and
selectivity of this reaction are discussed.
A. Carpita, L. Mannocci, R. Rossi, Eur. J. Org. Chem., 2005,
1367-1377.
L. Zani, S. Alesi, P. G. Cozzi, C. Bolm, J. Org. Chem.,
2006,
71, 1558-1562.
