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Aminocarbonylation

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Recent Literature

An efficient ligand-free protocol for the amincocarbonylation of aryl iodides with aromatic and aliphatic amines afforded the desired amides in excellent yields using a low loading of palladium(II) acetate as catalyst in water under mild operating conditions. The system tolerated a wide variety of hindered and functionalized substrates.
P. J. Tambade, Y. P. Patil, M. J. Bhanushali, B. M. Bhanage, Synthesis, 2008, 2347-2352.

A Pd-catalyzed aminocarbonylation of aryl bromides into the corresponding Weinreb amides at atmospheric pressure efficiently transforms eletron-deficient, - neutral, and -rich aryl bromides.
J. R. Martinelli, D. M. M. Freckmann, S. L. Buchwald, Org. Lett., 2006, 8, 4795-4797.

Molybdenum hexacarbonyl is a convenient and solid carbon monoxide source in a microwave-accelerated palladium-catalyzed aminocarbonylation of aryl bromides and iodides. 16 different aromatic amides were synthesized under air in good yields after only 15 min of controlled microwave irradiation.
J. Wannberg, M. Larhed, J. Org. Chem., 2003, 68, 5750-5753