Categories: C-O Bond Formation > Synthesis of alcohols (hydroxylation) >
Synthesis of 1,2-amino alcohols
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Name Reactions
Recent Literature
A N-heterocyclic carbene serves as an efficient catalyst for the
regioselective ring-opening reactions of aziridines in the presence of acid
anhydrides to afford the desired products in good to excellent yields.
X. Sun, S. Ye, J. Wu, Eur. J. Org. Chem., 2006,
4787-4790.
The chemoselective ring opening of N-tosyl aziridines with aldehydes
catalyzed by an N-heterocyclic carbene gave carboxylates of 1,2-amino alcohols. A plausible mechanism for this reaction is discussed.
Y.-K. Liu, R. Li, L. Yue, B.-J. Li, Y.-C. Chen, Y. Wu, L.-S. Ding, Org. Lett.,
2006,
8, 1521-1524.
Pd-catalyzed selective oxidation of Boc-protected N-methylamines
with IOAc as the oxidant involves a Boc-directed C-H activation process.
D.-H. Wang, X.-S. Hao, D.-F. Wu, J.-Q. Yu, Org. Lett.,
2006,
8, 3387-3390.
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