Categories: C-S Bond Formation >
Synthesis of allylic sulfides
Recent Literature

A nickel(0) triethyl phosphite complex promotes the reaction of allylic acetates
with thiols to produce allylic sulfides with retention of configuration without
allylic rearrangement. A similar reaction of allylic acetates with alcohols and
phenols also proceeds with retention of regio- and stereochemistry.
Y. Yatusmonji, Y. Ishida, A. Tsubouchi, T. Takeda, Org. Lett., 2007,
9, 4603-4606.
