Categories: C-S Bond Formation >
Synthesis of thiophenols
Name Reactions
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Recent Literature
A new synthetic method for the preparation of potassium
organotrifluoroborates through nucleophilic substitution of potassium bromo-
and iodomethyltrifluoroborates is described. Potassium
halomethyltrifluoroborates have been prepared via in situ reaction of n-BuLi
with dibromo- and diiodomethane, respectively, in the presence of trialkyl
borates, followed by treatment with KHF2.
G. A. Molander, J. Ham, Org. Lett.,
2006, 8, 2031-2034.
