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Synthesis of hydroxylamines and related compounds

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A copper-catalyzed electrophilic amination of simple and functionalized aryl, heteroaryl-, benzyl, n-alkyl, sec-alkyl, and tert-alkyl diorganozinc nucleophiles with R2NOC(O)Ph and RHNOC(O)Ph reagents as electrophilic nitrogen sources provides tertiary and secondary amines, respectively, in generally good yields.
A. M. Berman, J. S. Johnson, J. Org. Chem., 2006, 71, 219-224.