Categories: Synthesis of N-Heterocycles, Synthesis of S-Heterocycles >

Synthesis of sultams and related compounds

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Recent Literature

Highly strained β-sultams, sulfonyl analogues of β-lactams, were prepared enantio- and diastereoselectively by tertiary amine catalyzed [2 + 2] cycloaddition reactions. β-Sultams are practical precursors of highly enantioenriched β-aminosulfonyl derivatives of biological interest.
M. Zajac, R. Peters, Org. Lett., 2007, 9, 2007-2010.

Related: An efficient amidation reaction of saturated C-H bonds catalyzed by a unique disilver(I) complex is reported. The reaction is stereospecific and practical for the construction of amine-containing molecules. Y. Cui, C. He, Angew. Chem. Int. Ed., 2004, 43, 4210-4212.