Nonlinear stereochemical effects in asymmetric reactions.

M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, Tetrahedron: Asymmetry, 1997, 8, 2997.

Key Words:
ENANTIOSELECTIVE CONJUGATE ADDITION/CARBONYL-ENE REACTION/AUTOCATALYTIC REACTION/KINETIC RESOLUTION/CHIRAL ALKOXYDIMETHYLCUPRATE/ENANTIOMERIC PURITY/ALDOL CONDENSATION/ORGANIC-SYNTHESIS/TITANIUM COMPLEX/CYCLIC ENONES



M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, in Recent Research Developments in Organic Chemistry, Vol. 1 (Ed.: S. G. Pandalai), Transworld Research Network, Tc 36/248 1/Trivandrum 695008/India, 1997, pp. 159.

Key Words:



Synthetic variations based on low-valent chromium: new developments.

M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, Chem. Soc. Rev., 1999, 28, 169.

Key Words:
NI(II)/CR(II)-MEDIATED COUPLING REACTION/NOZAKI-HIYAMA REACTION/KISHI REACTION/ALDEHYDES/REAGENTS/HALIDES/CRCL2/CYCLIZATIONS/DERIVATIVES/CATALYSIS



Chiral autocatalysis: where stereochemistry meets the origin of life.

M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, J. Chem. Soc., Chem. Commun., 2000, 887.

Key Words:
ABSOLUTE ASYMMETRIC-SYNTHESIS/OCTAHEDRAL COBALT COMPLEX/SYMMETRY-BREAKING/ENANTIOMERIC RESOLUTION/BIOMOLECULAR HOMOCHIRALITY/STIRRED CRYSTALLIZATION/PREFERENTIAL ENRICHMENT/3-DIMENSIONAL CRYSTALS/SPONTANEOUS GENERATION/MURCHISON METEORITE



From parity to chirality: chemical implications revisited.

M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, Tetrahedron: Asymmetry, 2000, 11, 2845.

Key Words:
ABSOLUTE ASYMMETRIC-SYNTHESIS/VIOLATING ENERGY DIFFERENCES/CIRCULARLY-POLARIZED-LIGHT/OPTICALLY-ACTIVE MOLECULES/OCTAHEDRAL COBALT COMPLEX/MIRROR SYMMETRY-BREAKING/AMINO-ACIDS/STIRRED CRYSTALLIZATION/BIOMOLECULAR CHIRALITY/SPONTANEOUS RESOLUTION



Absolute asymmetric synthesis under physical fields: Facts and fictions.

M. Avalos, R. Babiano, P. Cintas, J. L. Jimenez, J. C. Palacios, L. D. Barron, Chem. Rev., 1998, 98, 2391.

Key Words:
CIRCULARLY-POLARIZED-LIGHT/STATIC MAGNETIC-FIELD/PROCHIRAL CHEMICAL-REACTIONS/OPTICAL-ACTIVITY/AMINO-ACIDS/MOLECULAR CHIRALITY/MURCHISON METEORITE/ENANTIOSELECTIVE REACTIONS/PHOTOCHEMICAL-REACTIONS/ABSORPTION-COEFFICIENT