Carbenoid complexes of electron-deficient transition metals - Syntheses of
and with short-lived building blocks.
R. Beckhaus, Angew. Chem., Int. Ed. Engl., 1997, 36, 687.
Key Words:
carbene complexes/cycloadditions/metallacycles/titanium/vinylidene complexes/C-H
ACTIVATION/MEDIATED CARBONYL OLEFINATIONS/METALLACYCLIC ZIRCONOXYCARBENE
COMPLEXES/AGOSTIC ALKENYLZIRCONOCENE COMPLEXES/TITANOCENE VINYLIDENE COMPLEXES/THERMAL-DECOMPOSITION
PATHWAYS/LINEAR SEMIBRIDGING CARBONYLS/ALPHA-HYDROGEN ABSTRACTION/FISCHER-TROPSCH
REACTION/SINGLE-SOURCE PRECURSOR
R. Beckhaus, in Metallocenes: Synthesis, Reactivity, Applications, Vol. 1 and
2 (Eds.: A. Togni, R. L. Halterman), Wiley-Vch, Inc, 605 Third Ave, New
York, NY 10158-0012, USA, 1998, pp. 153.
Key Words:
The story of 1-alkenyl complexes of early transition metals - A low
temperature access to the versatile titana-allene building block [Cp*Ti-2=C=CH2].
R. Beckhaus, J. Oster, J. Sang, I. Strauss, M. Wagner, Synlett, 1997,
241.
Key Words:
titanocene/vinylidene complexes/metathesis/metallacycles/binuclear complexes/FISCHER-CARBENE
COMPLEXES/CYCLOADDITION REACTIONS/VINYLIDENE/REACTIVITY/CHEMISTRY/ZIRCONIUM/VINYLLITHIUM/DERIVATIVES/TITANOCENE/TITANACYCLOBUTANE
Carbene complexes of titanium group metals - formation and reactivity.
R. Beckhaus, C. Santamaria, J. Organomet. Chem., 2001, 617,
81.
Key Words:
carbene complexes; titanium group metals; cycoladdition reactions;
TITANOCENE VINYLIDENE FRAGMENT; MEDIATED CARBONYL OLEFINATIONS;
ETA(2)-N-2-TITANIUM DIAZOALKANE COMPLEX; RING-OPENING METATHESIS; R = PH;
ALKYLIDENE COMPLEXES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; ZIRCONIUM
COMPLEXES; HETEROBINUCLEAR COMPLEXES