Catalytic asymmetric C-C bond formation: New enolato- and organolithium chemistry.

D. J. Berrisford, Angew. Chem., Int. Ed. Engl., 1995, 34, 178.

Key Words:
ASYMMETRIC SYNTHESIS/CATALYSIS/LITHIUM COMPOUNDS/ENANTIOSELECTIVE AUTOINDUCTION/LITHIUM ENOLATE/ALKYLATION/AMIDE/AGGREGATE/COMPLEX/LIGAND/IMINES/Li



Catalytic asymmetric carbonyl-ene reactions.

D. J. Berrisford, C. Bolm, Angew. Chem., Int. Ed. Engl., 1995, 34, 1717.

Key Words:
ASYMMETRIC SYNTHESES/CARBONYL-ENE REACTIONS/CATALYSIS/CHIRAL AUXILIARIES/TITANIUM COMPOUNDS/MECHANISM/Ti



Ligand-accelerated catalysis.

D. J. Berrisford, C. Bolm, K. B. Sharpless, Angew. Chem., Int. Ed. Engl., 1995, 34, 1059.

Key Words:
ASYMMETRIC SYNTHESES/CATALYSIS/DIHYDROXYLATIONS/EPOXIDATIONS/TITANIUM COMPOUNDS/CHIRAL TITANIUM COMPLEXES/TERT-BUTYL HYDROPEROXIDE/CARBONYL-ENE REACTION/DISULFONAMIDE-TI(O-ISO-PR)4-DIALKYL ZINC SYSTEM/HIGHLY ENANTIOSELECTIVE DIHYDROXYLATION/FUNCTIONALIZED SECONDARY ALCOHOLS/ASYMMETRIC EPOXIDATION CATALYSTS/DIELS-ALDER REACTION/OSMIUM-TETROXIDE/KINETIC RESOLUTION/Ti/Zn