Enantioselective transition metal-catalyzed hydrogenation for the asymmetric synthesis of amines.

C. Bolm, Angew. Chem., Int. Ed. Engl., 1993, 32, 232.

Key Words:
TM



C. Bolm, in Advanced Asymmetric Synthesis (Ed.: G. R. Stephenson), Chapman & Hall, London, U.K., 1996, pp. 9.

Key Words:



C. Bolm, in Advances in Catalytic Processes, Vol. 2 (Ed.: M. P. Doyle), Jai Press Inc, 55 Old Post Road/ No 2/Greenwich/CT 06836, 1997, pp. 43.

Key Words:



Asymmetric autocatalysis with amplification of chirality.

C. Bolm, F. Bienewald, A. Seger, Angew. Chem., Int. Ed. Engl., 1996, 35, 1657.

Key Words:
ENANTIOSELECTIVE AUTOINDUCTION/BIOMOLECULAR CHIRALITY/MOLECULAR REPLICATION/KINETIC RESOLUTION/GENERATION/CATALYSIS/ORIGIN/CRYSTALLIZATION/MULTIPLICATION/HOMOCHIRALITY



Polymer-supported catalytic asymmetric Sharpless dihydroxylations of olefins.

C. Bolm, A. Gerlach, Eur. J. Org. Chem., 1998, 21.

Key Words:
heterogeneous catalysis/homogeneous catalysis/asymmetric catalysis/dihydroxylation/polymers/PROCESS IMPROVEMENT/LIGAND CLASS/ALKENES/PROTEINS/LEADS/DERIVATIVES/EFFICIENT



Catalyzed asymmetric arylation reactions.

C. Bolm, J. P. Hildebrand, K. Muniz, N. Hermanns, Angew. Chem., Int. Ed. Engl., 2001, 40, 3285.

Key Words:
arylation; asymmetric synthesis; homogeneous catalysis; transition metals; QUATERNARY CARBON CENTERS; ENANTIOSELECTIVE HECK REACTIONS; CROSS-COUPLING REACTIONS; ALPHA-IMINO ESTERS; C-C BOND; REGIOSELECTIVE OLEFIN INSERTION; ACTIVE PALLADIUM CATALYSTS; CHIRAL AMINO ALCOHOL; IN-SITU GENERATION; ARYLBORONIC ACIDS



Planar chiral arene chromium(0) complexes: potential ligands for asymmetric catalysis.

C. Bolm, K. Muniz, Chem. Soc. Rev., 1999, 28, 51.

Key Words:
STEREOSELECTIVE SYNTHESIS/TRICARBONYLCHROMIUM COMPLEXES/ORGANOMETALLIC CHEMISTRY/ORGANIC-SYNTHESIS/(ETA-6-ARENE)CHROMIUM/ENANTIOSELECTIVITY/BENZANNULATION/METALATION