Organic Chemistry Portal

Abstracts

Search:



Alkyl, silyl, and phosphane ligands - Classical ligands in nonclassical bonding modes.

P. Braunstein, N. M. Boag, Angew. Chem., Int. Ed. Engl., 2001, 40, 2427.

Key Words:
alkyl ligands; bridging ligands; cluster compounds; dinuclear complexes; P ligands; Si ligands; X-RAY STRUCTURES; TRANSITION-METAL COMPLEXES; BRIDGING METHYL-GROUP; CRYSTAL-STRUCTURE; NEUTRON-DIFFRACTION; = PH; C-H; OLEFIN POLYMERIZATION; DINUCLEAR COMPLEXES; PALLADIUM(I) DIMER



Reactivity of the metal-silicon bond in organometallic chemistry.

P. Braunstein, M. Knorr, J. Organomet. Chem., 1995, 500, 21.

Key Words:
SILICON/METAL-SILICON BONDS/INSERTION REACTIONS/MIGRATION REACTIONS/DEHYDROGENATIVE DOUBLE SILYLATION/INTRAMOLECULAR BIS-SILYLATION/CARBON UNSATURATED-COMPOUNDS/X-RAY STRUCTURE/PHOTOCHEMICAL-REACTIONS/PRIMARY ORGANOSILANES/TRANSITION-METALS/RHODIUM(I)-CATALYZED HYDROSILYLATION/BIS(HYDROSILANE) COMPOUNDS/CATALYZED HYDROSILATION/Si/Rh/TM



Bimetallic silicon chemistry - New opportunities in coordination and organometallic chemistry.

P. Braunstein, M. Knorr, C. Stern, Coord. Chem. Rev., 1998, 180, 903.

Key Words:
alkoxysilanes/aminosilanes/catalytic dehydrogenative coupling of stannanes/CO-olefin stepwise insertion/hemilabile behaviour/heterobimetallic/isonitrile insertion reactions/redistribution reactions/silicon migration reactions/siloxanes/mu-siloxycarbene complexes/silylene/stannylene complexes/TRANSITION-METAL-COMPLEXES/RAY CRYSTAL-STRUCTURE/SILYLENE SILANEDIYL COMPLEXES/CATALYZED ALTERNATING COPOLYMERIZATION/INTRAMOLECULAR BASE STABILIZATION/BRIDGED BIS(SILYLENE)IRON COMPLEX/CORRESPONDING ANIONIC COMPLEXES/MIGRATORY INSERTION REACTIONS/CARBON-MONOXIDE INSERTION/POLYSILANE HIGH POLYMERS



Dehydrogenative coupling of hydrostannanes catalyzed by transition-metal complexes.

P. Braunstein, X. Morise, Chem. Rev., 2000, 100, 3541.

Key Words:
BOND METATHESIS MECHANISM/ELEMENT-ELEMENT BONDS/SUBSTITUTED TIN ATOMS/ELECTROCHEMICAL SYNTHESIS/ORGANOMETALLIC CHEMISTRY/POLYURETHANE PREPARATION/MOLECULAR ARCHITECTURE/ORGANOTIN CHEMISTRY/POLYMERS/POLYSTANNANES



Hemilability of hybrid ligands and the coordination chemistry of oxazoline-based systems.

P. Braunstein, F. Naud, Angew. Chem., Int. Ed. Engl., 2001, 40, 680.

Key Words:
coordination chemistry; homogeneous catalysis; hybrid ligands; ligand design; sensors; ASYMMETRIC TRANSFER HYDROGENATION; TRANSITION-METAL COMPLEXES; CATALYZED ALLYLIC SUBSTITUTION; RHENIUM(I) CARBONYL-COMPLEXES; PHOSPHINO ENOLATE LIGANDS; C-2-SYMMETRICAL BINUCLEATING LIGANDS; MIGRATORY INSERTION REACTIONS; CATIONIC PALLADIUM COMPLEXES; NUCLEAR-MAGNETIC-RESONANCE; CHIRAL RUTHENIUM COMPLEXES



Transition-metal-mediated reactions of organic isocyanates.

P. Braunstein, D. Nobel, Chem. Rev., 1989, 89, 1927.

Key Words:
TM



P. Braunstein, J. Rose, in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 10 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, UK, 1995, pp. 351.

Key Words:



P. Braunstein, J. Rose, in Catalysis by di- and Polynuclear Metal Cluster Complexes (Eds.: R. D. Adams, F. A. Cotton), Wiley-VCH, Inc, 605 Third Ave/New York/NY 10158-0012, 1998, pp. 443.

Key Words: