Explorations in The Non-classical Ion Area.

H. C. Brown, Tetrahedron, 1976, 32, 179.

Key Words:
PHYSICAL ORGANIC/REACTIVE INTERMEDIATES/CARBONIUM IONS/CARBOCATIONS/C+



H. C. Brown, in Comprehensive Organometallic Chemistry, Vol. 7 (Eds.: G. Wilkinson, F. G. A. Stone, E. Abel), Pergamon, Oxford, 1982, p. 111.

Key Words:
ORGANOMETALLICS/BORON/B



Investigations in the synthesis of alkyl-substituted borohydrides.

H. C. Brown, J. Organomet. Chem., 1982, 239, 43.

Key Words:
ORGANOMETALLICS/BORON/BOROHYDRIDES/B



Asymmetric synthesis made easy.

H. C. Brown, Chemtracts: Organic Chemistry, 1988, 1, 77.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/BORON/B



H. C. Brown, in Studies in Natural Products Chemistry, Vol.8: Stereoselective Synthesis, Part E (Ed.: Atta-ur-Rahman), Elsevier, Amsterdam, Netherlands, 1991, pp. 463.

Key Words:
BORON/B



Synthesis and Reactions of Vinylic Organoboranes.

H. C. Brown, J. B. Campbell, Aldrichimica Acta, 1981, 14, 3.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/HETEROALKENES/ACETYLENES/C=C-M/B/HYDROMETALLATION/B/ALKENYL HALIDES/C=C-M/B



H. C. Brown, P. K. Jadhav, in Asymmetric Synthesis, Vol. 2 (Ed.: J. D. Morrison), AP, New York, 1983, p. 1.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/ORGANOMETALLICS/BORON/C=C/ALKENES/BORANES/HYDROBORATION/HYDROMETALLATION/B/ENANTIOSELECTIVE/C-OH



Asymmetric Synthesis via Chiral Organoborane Reagents.

H. C. Brown, P. K. Jadhav, A. K. Mandal, Tetrahedron, 1981, 37, 3547.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/C-M/B/HYDROMETALLATION/REDUCTION



Forty Years of Hydride Reductions.

H. C. Brown, S. Krishnamurthy, Tetrahedron, 1979, 35, 567.

Key Words:
FUNCTIONAL GROUPS/REDUCTION/METAL HYDRIDE/HYDRIDES/REDUCTION



Haloboranes and their alkyl derivatives.

H. C. Brown, S. U. Kulkarni, J. Organomet. Chem., 1982, 239, 1.

Key Words:
ORGANOMETALLICS/BORON/HALOBORANES/B



Organic Synthesis via Free-Radical Displacement Reactions of Organoboranes.

H. C. Brown, M. M. Midland, Angew. Chem., Int. Ed. Engl., 1972, 11, 692.

Key Words:
PHYSICAL ORGANIC/REACTIVE INTERMEDIATES/RADICALS/B



The boron approach to asymmetric synthesis.

H. C. Brown, P. V. Ramachandran, Pure Appl. Chem., 1991, 63, 307.

Key Words:
B



Asymmetric reduction with chiral organoboranes based on alpha-pinene.

H. C. Brown, P. V. Ramachandran, Acc. Chem. Res., 1992, 25, 16.

Key Words:
B



Recent advances in the boron route to asymmetric synthesis.

H. C. Brown, P. V. Ramachandran, Pure Appl. Chem., 1994, 66, 201.

Key Words:
B



H. C. Brown, P. V. Ramachandran, in Advances in Asymmetric Synthesis, Vol. 1 (Ed.: A. Hassner), Jai Press Inc, Greenwich, CT, 1995, pp. 147.

Key Words:
B/BORON



Versatile alpha-pinene-based borane reagents for asymmetric syntheses.

H. C. Brown, P. V. Ramachandran, J. Organomet. Chem., 1995, 500, 1.

Key Words:
ASYMMETRIC SYNTHESES/BORON/BORANE REAGENTS/ALPHA-PINENE/HIGH OPTICAL PURITY/HIGH ENANTIOMERIC PURITIES/ENANTIOSELECTIVE ALDOL REACTIONS/B-3-PINANYL-9-BBN ALPINE-BORANE/STRUCTURALLY RELATED-COMPOUNDS/ACTIVE NATURAL CAROTENOIDS/CHIRAL HYDROBORATING AGENT/LITHIUM ALUMINUM-HYDRIDE/ONE-CARBON HOMOLOGATION/PURE BORINIC ESTERS/B



Development of a Simple Procedure for Synthesis of Pure Enantiomers via Chiral Organoboranes.

H. C. Brown, B. Singaram, Acc. Chem. Res., 1988, 21, 287.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/ORGANOMETALLICS/BORON/MONOISOPINYLCAMPHEYLBORANE/DIISOPINOCAMPHEYLBORANE/MONOISOPINOCAMPHEYLBORANE/HYDROMETALLATION/B/ENANTIOSELECTIVE/C=C/DISUB/E/C-X/N/C-X/O/KETONES



Hydroboration of Heterocyclic Olefins. A Versatile Route for the Synthesis of Both Racemic and Optically Active Heterocyclic Compounds.

H. C. Brown, J. V. N. Vara Prasad, Heterocycles, 1987, 25, 641.

Key Words:
C-C BOND FORMATION/HETEROANNULATIONS/C=C-X/O/HYDROMETALLATION/B/HYDROBORATION/HETEROCYCLES