Stereoselective synthesis of quaternary alpha-amino acids. Part 1: Acyclic compounds.

C. Cativiela, M. D. DiazdeVillegas, Tetrahedron: Asymmetry, 1998, 9, 3517.

Key Words:
BETA-KETO-ESTERS/SOLUTION CONFORMATIONAL-ANALYSIS/ENOLATE CLAISEN REARRANGEMENT/ASYMMETRIC STRECKER-SYNTHESIS/CHIRAL AUXILIARY REAGENT/NICKEL(II) SCHIFF-BASE/DE-NOVO DESIGN/SCALEMIC 3,5,5-TRISUBSTITUTED PYRROLIN-4-ONES/OPTICALLY-ACTIVE 3-AMINO-2H-AZIRINES/PHASE-TRANSFER CATALYSIS



Stereoselective synthesis of quaternary alpha-amino acids. Part 2. Cyclic compounds.

C. Cativiela, M. D. DiazdeVillegas, Tetrahedron: Asymmetry, 2000, 11, 645.

Key Words:
DIELS-ALDER REACTIONS/RING-CLOSING METATHESIS/INTRAMOLECULAR STRECKER SYNTHESIS/METABOTROPIC GLUTAMATE RECEPTORS/ENANTIOSELECTIVE TOTAL SYNTHESES/ENHANCED ANTIOPIATE ACTIVITY/ENANTIOMERICALLY PURE FORM/BIS-LACTIM ETHERS/ASYMMETRIC-SYNTHESIS/C-ALPHA,ALPHA-DIALKYLATED GLYCINES



Modelling of solvent effects on the Diels-Alder reaction.

C. Cativiela, J. I. Garcia, J. A. Mayoral, L. Salvatella, Chem. Soc. Rev., 1996, 25, 209.

Key Words:
HOST-GUEST CHEMISTRY/ENDO/EXO-SELECTIVITIES/COMPUTER-SIMULATIONS/STEREOSELECTIVITY/WATER/CYCLOADDITIONS/1,3-DIENES