Redox induced radical and radical ionic carbon-carbon bond forming reactions.

P. I. Dalko, Tetrahedron, 1995, 51, 7579.

Key Words:
SINGLE-ELECTRON-TRANSFER/LOW-VALENT TITANIUM/TRIMETHYLSILYL ENOL ETHERS/ZINC-PROMOTED REACTIONS/BETA-KETO-ESTERS/ATOM TRANSFER CYCLIZATION/FLUORO ACID-MEDIUM/BISBENZOCYCLOOCTADIENE LIGNAN LACTONES/RUTHENIUM-CATALYZED CYCLIZATION/INDUCED OXIDATIVE DESILYLATION/SILICON/Si/Ti/Zn/Ru



Enantioselective organocatalysis.

P. I. Dalko, L. Moisan, Angew. Chem., Int. Ed. Engl., 2001, 40, 3726.

Key Words:
asymmetric catalysis; chiral auxiliaries; synthetic methods; CATALYTIC ASYMMETRIC EPOXIDATION; PHASE-TRANSFER CATALYSIS; BAYLIS-HILLMAN REACTION; ALPHA-AMINO-ACIDS; QUATERNARY AMMONIUM SALT; DIELS-ALDER REACTIONS; CHIRAL LEWIS-BASES; NONENZYMATIC KINETIC RESOLUTION; FRUCTOSE-DERIVED DIOXIRANE; RACEMIC SECONDARY ALCOHOLS



Recent advances in the conversion of carbohydrate furanosides and pyranosides into carbocycles.

P. I. Dalko, P. Sinay, Angew. Chem., Int. Ed. Engl., 1999, 38, 773.

Key Words:
C-C coupling/carbocycles/carbohydrates/cyclitols/cyclizations/D-ISOGLUTAMINE MDP/ENANTIOMERICALLY PURE/RING CONTRACTION/ENANTIOSELECTIVE SYNTHESIS/GLUCOSIDASE INHIBITOR/ORGANIC-SYNTHESIS/(-)-QUINIC ACID/PSEUDO-SUGARS/DERIVATIVES/ANALOGS