Cycloaddition and cyclocondensation reactions of highly functionalized dienes: Applications to organic synthesis.

S. Danishefsky, Chemtracts: Organic Chemistry, 1989, 2, 273.

Key Words:



From the laboratory to the clinic: A retrospective on fully synthetic carbohydrate-based anticancer vaccines.

S. J. Danishefsky, J. R. Allen, Angew. Chem., Int. Ed. Engl., 2000, 39, 837.

Key Words:
carbohydrates/drug research/glycoconjugates/tumor therapy/vaccines/ACTIVE SPECIFIC IMMUNOTHERAPY/TUMOR-BEARING MICE/SIALYL-LEWIS-X/ANION-EXCHANGE CHROMATOGRAPHY/LACTONEO-SERIES ANTIGENS/BREAST-CANCER ANTIGEN/CELL-SURFACE GLYCANS/GLOBO-H-ANTIGEN/MELANOMA PATIENTS/MONOCLONAL-ANTIBODIES



Glycals in organic synthesis: The evolution of comprehensive strategies for the assembly of oligosaccharides and glycoconjugates of biological consequence.

S. J. Danishefsky, M. T. Bilodeau, Angew. Chem., Int. Ed. Engl., 1996, 35, 1380.

Key Words:
GLYCALS/GLYCOCONJUGATES/GLYCOSYLATIONS/OLIGOSACCHARIDES/SYNTHETIC METHODS/SIALYL-LEWIS-X/LEUKOCYTE ADHESION MOLECULE-1/CHEMICAL-ENZYMATIC SYNTHESIS/TRIFUCOSYLATED TYPE-2 CHAIN/N-LINKED GLYCOPEPTIDES/SOLID-PHASE SYNTHESIS/BLOOD-GROUP ANTIGENS/HUMAN ADENOCARCINOMA/STEREOSELECTIVE SYNTHESIS/BRANCHED OLIGOSACCHARIDE



Advances in the development of convergent schemes for the synthesis of biologically important glycoconjugates.

S. J. Danishefsky, J. Y. Roberge, Pure Appl. Chem., 1995, 67, 1647.

Key Words:
GLYCALS/OLIGOSACCHARIDES/GLYCOSYLATION/GLYCOPEPTIDES/SULFONAMIDOGLYCOSYLATION/GLYCOBIOLOGY/GLYCOSIDES/STRATEGY/DOMAINS/ANTIGEN



Chemical explorations driven by an enchantment with mitomycinoids - A twenty year account.

S. J. Danishefsky, J. M. Schkeryantz, Synlett, 1995, 475.

Key Words:
MITOMYCINOID/MITOMYCIN C/MITOMYCIN K/FR-900482/ANTIBIOTIC/ANTITUMOR/LEUCOMITOMYCIN/AZIRIDINOMITOSENE/DNA CROSS-LINKING/ACTIVATION CASCADE/NITROSO-COMPOUNDS/EFFICIENT ROUTE/ISOMITOMYCIN-A/FR-900482/MITOSENE/DERIVATIVES/CONGENERS/REDUCTION



Synthetic studies in the mevinoid field. The total synthesis of ML236A.

S. J. Danishefsky, B. Simoneau, Pure Appl. Chem., 1988, 60, 1555.

Key Words:



Electrophilic Cyclopropanes in Organic Synthesis.

S. Danishevsky, Acc. Chem. Res., 1979, 12, 66.

Key Words:
FUNCTIONAL GROUPS/TRANSFORMATIONS/CYCLOPROPANE CLEAVAGE/CARBRING/3



Siloxy Dienes in Total Synthesis.

S. Danishevsky, Acc. Chem. Res., 1981, 14, 400.

Key Words:
C-C BOND FORMATION/PERICYCLIC REACTIONS/CYCLOADDITIONS/[4+2]/SILOXY DIENES ALDEHYDES C=C-X-M/O-Si/DANISHEVSKY DIENE/TETRAHYDROPYRAN-4-ONES/HETRING/6(O)/Si



Reflections on Organic Synthesis: The Evolution of a General Strategy for the Stereoselective Construction of Polyoxygenated Natural Products.

S. J. Danishevsky, Aldrichimica Acta, 1986, 19, 59.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC/DIASTEREOGENIC/PERICYCLIC REACTIONS/CYCLOADDITIONS/[4+2]/TARGET SYNTHESIS/STEREOCHEMISTRY/C=C-C(X)=C/O-Si/DANISHEVSKY DIENE/ALDOL/DIHYDROPYRONE HETRING/6(O)