D. Enders, in Asymmetric Synthesis. Stereodifferentiating Reactions, Part B., Vol. 3 (Ed.: J. D. Morrison), AP, New York, 1984, p. 275.

Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/ENANTIOGENIC REACTIONS/CHIRAL AUXILIARY/C=N-X/N/C=C-X-M/N-Li/CHIRAL HYDRAZONES/ENANTIOSELECTIVE/1,2-ADDITION/(C=Z,X-Y)/CHIRAL AUXILIARY/O=C(R)-C-C-X/C,OH/O=C(R)-C-C-X/OR,OH/DICARBONYLS/1,3/C-X



alpha-silyl ketone controlled asymmetric syntheses.

D. Enders, J. Adam, D. Klein, T. Otten, Synlett, 2000, 1371.

Key Words:
asymmetric synthesis/hydrazones/organosilicon compounds/Michael additions/aldol reactions/METALATED CHIRAL HYDRAZONES/ENANTIOSELECTIVE SYNTHESIS/STEREOSELECTIVE SYNTHESIS/AGGREGATION PHEROMONE/FLUOROORGANIC COMPOUNDS/CARBONYL-COMPOUNDS/ORGANIC-SYNTHESIS/CYCLIC SULFATES/ALDOL REACTIONS/ALDEHYDES



Recent advances in the development of highly enantioselective synthetic methods.

D. Enders, W. Bettray, Pure Appl. Chem., 1996, 68, 569.

Key Words:
ENZYMATIC ALDOL CONDENSATION/ALDEHYDE-SAMP HYDRAZONES/ASYMMETRIC-SYNTHESIS/NUCLEOPHILIC 1,2-ADDITION/HIV-1 PROTEASE/AMINO ACETALS/INHIBITORS/ENANTIOMERS/AZASUGARS/SUGARS



Synthesis of chiral triazolinylidene and imidazolinylidene transition metal complexes and first application in asymmetric catalysis.

D. Enders, H. Gielen, J. Organomet. Chem., 2001, 617, 70.

Key Words:
nucleophilic carbenes; chiral triazolinylidenes; chiral imidazolinylidenes; immobilized triazolium salts; asymmetric catalysis; ELECTRON-RICH OLEFINS; CARBENE COMPLEXES; STABLE CARBENE; (TRIAZOLINYLIDENE)RHODIUM COMPLEXES; ENANTIOSELECTIVE HYDROSILYLATION; DIASTEREOSELECTIVE SYNTHESIS; PHOTOCHEMICAL-REACTIONS; HOMOGENEOUS CATALYSIS; LIGAND; 1,3,4-TRIPHENYL-4,5-DIHYDRO-1H-1,2,4-TRIAZOL-5-YLIDENE



Synthesis of highly enantioenriched compounds via iron mediated allylic substitutions.

D. Enders, B. Jandeleit, S. vonBerg, Synlett, 1997, 421.

Key Words:
SOUTHERN CORN-ROOTWORM/METAL-COORDINATED OLEFINS/BANDED CUCUMBER BEETLE/ENANTIOSELECTIVE SYNTHESIS/SEX-PHEROMONE/ASYMMETRIC-SYNTHESIS/CHIRALITY TRANSFER/PSEUDODISTOMA-NOVAEZELANDIAE/TETRACARBONYLIRON COMPLEXES/CONVERGENT SYNTHESIS



''Chirality transfer'' in iron-mediated dienylic substitutions via highly enantiomerically enriched planar chiral 1-phenylsulfonyl-substituted tricarbonyl(eta(5)-pentadienyl)iron(1+) complexes.

D. Enders, B. Jandeleit, S. vonBerg, J. Organomet. Chem., 1997, 533, 219.

Key Words:
iron/tricarbonyl(eta(4)-diene)iron(0) complex/tricarbonyl(eta(5)-pentadienyl)iron(1+)complex/planar chirality/dienylic substitution/chirality transfer/ACTIVE TRICARBONYLIRON COMPLEXES/ACID-CATALYZED BENZYLATION/5-HETE METHYL-ESTER/BETA-LACTONE MOIETY/ASYMMETRIC-SYNTHESIS/TRICARBONYL(PENTADIENYL)IRON(1+) CATIONS/STEREOSELECTIVE SYNTHESIS/(DIENE)FE(CO)3 COMPLEXES/NUCLEOPHILIC-ADDITION/ALLYLIC SUBSTITUTIONS



Asymmetric synthesis with (S)-2-methoxymethylpyrrolidine (SMP) - A pioneer auxiliary.

D. Enders, M. Klatt, Synthesis, 1996, 1403.

Key Words:
ASYMMETRIC SYNTHESIS/ENANTIOSELECTIVE SYNTHESIS/CHIRAL AUXILIARY/(S)-2-METHOXYMETHYLPYRROLIDINE (SMP)/REVIEW/CHIRAL HOMOENOLATE EQUIVALENTS/HIGHLY ENANTIOSELECTIVE SYNTHESIS/DIELS-ALDER CYCLOADDITIONS/ADDITION ELIMINATION PROCESS/ORGANO-SILICON COMPOUNDS/CONJUGATE ADDITION/ORGANOSILICON COMPOUNDS/STEREOSELECTIVE ALKYLATIONS/ACYLNITROSO DIENOPHILES/ENAMINE ALKYLATION



Asymmetric [3.3]-sigmatropic rearrangements in organic synthesis.

D. Enders, M. Knopp, R. Schiffers, Tetrahedron: Asymmetry, 1996, 7, 1847.

Key Words:
ACCELERATED CLAISEN REARRANGEMENTS/CHIRAL ORGANOALUMINUM REAGENT/N-ALLYLKETENE N,O-ACETALS/ALPHA-AMINO-ACIDS/VICINAL QUATERNARY/INDUCTION/(-)-ISOIRIDOMYRMECIN/STEREOCONTROL/DERIVATIVES/ESTERS



Diastereo- and enantioselective Diels-Alder reactions of 2-amino-1,3-dienes.

D. Enders, O. Meyer, Liebigs Ann. Chem., 1996, 1023.

Key Words:
2-AMINO-1,3-DIENES/ENAMINES, CROSS CONJUGATED/[4 + 2] CYCLOADDITIONS/NITROCYCLOHEXANONES/4-PIPERIDINONES/CYCLOHEPTANDIONE DERIVATIVES/DANISHEFSKY DIENES/STEREOSELECTIVE SYNTHESIS/CATALYTIC AMINOMERCURIATION/CHIRAL 2-AMINO-1,3-DIENES/TERMINAL ACETYLENES/4+2 CYCLOADDITION/AROMATIC-AMINES/DERIVATIVES/2-AMINO-1,3-BUTADIENES/2-MORPHOLINOBUTADIENES/4-NITROCYCLOHEXANONES



Asymmetric synthesis of amines by nucleophilic 1,2-addition of organometallic reagents to the CN-double bond.

D. Enders, U. Reinhold, Tetrahedron: Asymmetry, 1997, 8, 1895.

Key Words:
ALPHA-SUBSTITUTED PHENETHYLAMINES/HIGHLY DIASTEREOSELECTIVE ADDITION/ALDEHYDE-SAMP HYDRAZONES/CHIRAL HOMOALLYL AMINES/ALLYLIC BORON-COMPOUNDS/NITROGEN DOUBLE-BONDS/ENANTIOSELECTIVE SYNTHESIS/STEREOSELECTIVE SYNTHESIS/ORGANOLITHIUM REAGENTS/ORGANOCERIUM ADDITIONS



Some recent applications of alpha-amino nitrile chemistry.

D. Enders, J. P. Shilvock, Chem. Soc. Rev., 2000, 29, 359.

Key Words:
ASYMMETRIC NUCLEOPHILIC ACYLATION/ENANTIOSELECTIVE SYNTHESIS/STRECKER SYNTHESIS/MICHAEL ADDITION/STEREOSELECTIVE SYNTHESIS/ENANTIOPURE SULFINIMINES/CARBOHYDRATE TEMPLATES/CN(R,S) METHOD/AMINONITRILES/ACIDS



Efficient stereoselective syntheses of piperidine, pyrrolidine, and indolizidine alkaloids.

D. Enders, C. Thiebes, Pure Appl. Chem., 2001, 73, 573.

Key Words:
ENANTIOSELECTIVE TOTAL SYNTHESES; BEETLE



Recovery of carbonyl compounds from N,N-dialkylhydrazones.

D. Enders, L. Wortmann, R. Peters, Acc. Chem. Res., 2000, 33, 157.

Key Words:
ENANTIOSELECTIVE SYNTHESIS/ASYMMETRIC-SYNTHESIS/OXIDATIVE CLEAVAGE/ALDEHYDE N,N-DIMETHYLHYDRAZONES/MAGNESIUM MONOPEROXYPHTHALATE/HYDRAZONE HYDROLYSIS/SODIUM PERBORATE/SAMP-HYDRAZONES/KETONES/NITRILES