Selective Transformations of Small Ring Compounds in Redox Reactions.

T. Hirao, Top. Curr. Chem., 1996, 178, 99.

Key Words:



Vanadium in modern organic synthesis.

T. Hirao, Chem. Rev., 1997, 97, 2707.

Key Words:
HYDROGEN-EVOLVING SYSTEMS/LOW-VALENT VANADIUM/TRANSITION-METAL COMPLEXES/OXIDATIVE DECARBOXYLATION-DEOXYGENATION/TRIMETHYLSILYL ENOL ETHERS/TERT-BUTYL HYDROPEROXIDE/DIELS-ALDER REACTIONS/X-RAY ABSORPTION/ONE-ELECTRON/MOLECULAR NITROGEN



A catalytic system for reductive transformations via one-electron transfer.

T. Hirao, Synlett, 1999, 175.

Key Words:
catalyst/one-electron reduction/pinacol coupling/radical/redox/LOW-VALENT VANADIUM/ABC RING-SYSTEM/ORGANIC-SYNTHESIS/COUPLING REACTIONS/CARBONYL-COMPOUNDS/TITANIUM CATALYST/PEPTIDE ALDEHYDES/PINACOL/CYCLIZATION/COMPLEX



Conjugated systems composed of transition metals and redox- active pi-conjugated ligands

T. Hirao, Coord. Chem. Rev., 2002, 226, 81.

Key Words:
pi-conjugated molecules/pi-conjugated polymers/redox-active ligands/conjugated complexes/multi-redox systems/reversible redox cycle palladium-catalyzed 1;4-diacetoxylation/molecular-oxygen/synthetic metal/electrochemical properties/dehydrogenative oxidation/magnetic-properties/semiquinone ligands/aerobic oxidations/optical-properties/electron-transfer