Rare-Earth-Metal Trifluoromethanesulfonates As Water-Tolerant Lewis-Acid Catalysts In Organic-Synthesis.

S. Kobayashi, Synlett, 1994, 689.

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New types of Lewis acids used in organic synthesis.

S. Kobayashi, Pure Appl. Chem., 1998, 70, 1019.

Key Words:
DIELS-ALDER REACTIONS/SINGLE CHIRAL SOURCE/STEREOSELECTIVE SYNTHESIS/ACHIRAL LIGANDS/TRIFLUOROMETHANESULFONATES/ENANTIOMERS/ACYLATION/YTTERBIUM/CATALYSTS/IMINES



S. Kobayashi, in Aqueous Phase Organometallic Catalysis (Eds.: B. Cornils, W. A. Herrmann), Wiley-Vch, Inc, 605 Third Ave, New York, NY 10158-0012, USA, 1998, pp. 519.

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New methodologies for the synthesis of compound libraries.

S. Kobayashi, Chem. Soc. Rev., 1999, 28, 1.

Key Words:
SUPPORTED SCANDIUM CATALYST/AMINO ALCOHOL LIBRARY/SILYL ENOL ETHERS/SOLID-PHASE/STEREOSELECTIVE SYNTHESIS/QUINOLINE DERIVATIVES/3-COMPONENT REACTIONS/LANTHANIDE TRIFLATE/ORGANIC-SYNTHESIS/ALDOL REACTIONS



Scandium triflate in organic synthesis.

S. Kobayashi, Eur. J. Org. Chem., 1999, 15.

Key Words:
Lewis acid/stereoselective reaction/organic synthesis/catalyst/DIELS-ALDER REACTIONS/SILYL ENOL ETHERS/LEWIS-ACID CATALYST/ASYMMETRIC 1,3-DIPOLAR CYCLOADDITION/KETENE BIS(TRIMETHYLSILYL) ACETALS/FRIEDEL-CRAFTS ALKYLATION/HIGH-RATE ACCELERATION/AMINO ALCOHOL LIBRARY/CARBON BOND FORMATION/MANNICH-TYPE REACTION



S. Kobayashi, in Lewis Acid Reagents (Ed.: H. Yamamoto), Oxford Univ Press, 198 Madison Avenue, New York, NY 10016, USA, 1999, pp. 137.

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S. Kobayashi, in Combinatorial Chemistry (Ed.: H. Fenniri), Oxford Univ Press, 2000, pp. 421.

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S. Kobayashi, in Cycloaddition Reactions in Organic Synthesis (Eds.: S. Kobayashi, K. A. Jorgensen), Wiley-Vch, Inc, 605 Third Ave/New York/NY 10158-0012/USA, 2002, pp. 187.

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New methods for high-throughput synthesis.

S. Kobayashi, R. Akiyama, Pure Appl. Chem., 2001, 73, 1103.

Key Words:
SUPPORTED SCANDIUM CATALYST; COMBINATORIAL SYNTHESIS; OSMIUM CATALYST; LIBRARIES; DIHYDROXYLATION; OLEFINS; ACID



Catalytic enantioselective addition to imines.

S. Kobayashi, H. Ishitani, Chem. Rev., 1999, 99, 1069.

Key Words:
DIELS-ALDER REACTIONS/ALPHA-AMINO-ACIDS/ASYMMETRIC STRECKER-SYNTHESIS/MANNICH-TYPE REACTIONS/TAXOL SIDE-CHAIN/KETENE BIS(TRIMETHYLSILYL) ACETALS/RHODIUM-PHOSPHINE COMPLEXES/ACTIVE COBALT(II) COMPLEXES/CHIRAL TITANOCENE CATALYST/BOUND PEPTIDE LIBRARIES



Development of novel Lewis acid catalysts for selective organic reactions in aqueous media

S. Kobayashi, K. Manabe, Acc. Chem. Res., 2002, 35, 209.

Key Words:
SURFACTANT-COMBINED CATALYST/DIELS-ALDER REACTION/SILYL ENOL ETHERS/ALPHA-AMINO PHOSPHONATES/COMMERCIAL FORMALDEHYDE SOLUTION/COLLOIDAL DISPERSION SYSTEM/ASYMMETRIC ALDOL REACTIONS/BOND-FORMING REACTIONS/MANNICH-TYPE REACTIONS/WATER



S. Kobayashi, K. Manabe, H. Ishitani, J.-I. Matsuo, in Organometallics: Compounds of Group 15 (As, Sb, Bi) and Silicon Compounds, Vol. 4 (Ed.: I. Fleming), Georg Thieme Verlag, Stuttgart - New York, 2002, pp. 317.

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Synthetic study on an antitumor antibiotic rhizoxin by using an enzymic process on prochiral ß-substituted glutarates.

S. Kobayashi, M. Nakada, M. Ohno, Pure Appl. Chem., 1992, 64, 1121.

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Rare-earth metal triflates in organic synthesis

S. Kobayashi, M. Sugiura, H. Kitagawa, W. W. L. Lam, Chem. Rev., 2002, 102, 2227.

Key Words:
DIELS-ALDER REACTIONS/SILYL ENOL ETHERS/LEWIS-ACID CATALYST/ONE-POT SYNTHESIS/FRIEDEL-CRAFTS ALKYLATION/PICTET-SPENGLER REACTION/BAYLIS-HILLMAN REACTION/1,3-DIPOLAR CYCLOADDITION REACTIONS/MANNICH-TYPE REACTION/ALIPHATIC CLAISEN REARRANGEMENT



Artificial urushi.

S. Kobayashi, H. Uyama, R. Ikeda, Chem. Eur. J., 2001, 7, 4755.

Key Words:
artificial urushi; enzyme catalysis; polymerization; renewable resource; urushiol analogues; OXIDATIVE POLYMERIZATION; ENZYMATIC POLYMERIZATION; SOLUBLE POLYPHENOL; ORIENTAL LACQUER; SHELL LIQUID; PEROXIDASE; CHEMISTRY; POLYMERS; CATALYST; ANALOGS