Organic Chemistry Portal

Abstracts

Search:



Carbene methods for the introduction of acyl and acylmethyl groups into organic molecules.

O. G. Kulinkovich, Russ. Chem. Rev. (Engl. Transl.), 1989, 58, 711.

Key Words:



Activated cyclopropanes in the synthesis of five-membered carbocycles and heterocycles.

O. G. Kulinkovich, Russ. Chem. Rev. (Engl. Transl.), 1993, 62, 839.

Key Words:



Alkylation of carbonyl compounds through conversion into oxycyclopropane intermediates.

O. G. Kulinkovich, Pol. J. Chem., 1997, 71, 849.

Key Words:
carbonyl compounds/alkylation/cyclopropanol derivatives/ring opening/SILYL ENOL ETHERS/ALPHA-METHYLENE KETONES/BOND-FORMING REACTIONS/ONE-POT SYNTHESIS/ORGANIC-SYNTHESIS/DIASTEREOSELECTIVE SYNTHESIS/CARBOXYLIC ESTERS/ACID-CHLORIDES/1-SUBSTITUTED CYCLOPROPANOLS/SUBSTITUTED CYCLOPROPANES



Titanacyclopropanes as versatile intermediates for carbon-carbon bond formation in reactions with unsaturated compounds.

O. G. Kulinkovich, Pure Appl. Chem., 2000, 72, 1715.

Key Words:
HALIDES/ESTERS



1,n-dicarbanionic titanium intermediates from monocarbanionic organometallics and their application in organic synthesis.

O. G. Kulinkovich, A. deMeijere, Chem. Rev., 2000, 100, 2789.

Key Words:
LOW-VALENT-TITANIUM/NUCLEOPHILIC ACYL SUBSTITUTION/MEDIATED CARBONYL OLEFINATIONS/HIGHLY EFFICIENT SYNTHESIS/RAY CRYSTAL-STRUCTURE/TITANOCENE VINYLIDENE COMPLEXES/ISOPROPOXIDE-CATALYZED REACTION/TRANSITION-METAL COMPLEXES/OPTICALLY-ACTIVE COMPLEXES/I-PRMGCL REAGENT