Carbene methods for the introduction of acyl and acylmethyl groups into
organic molecules.
O. G. Kulinkovich, Russ. Chem. Rev. (Engl. Transl.), 1989, 58,
711.
Key Words:
Activated cyclopropanes in the synthesis of five-membered carbocycles and
heterocycles.
O. G. Kulinkovich, Russ. Chem. Rev. (Engl. Transl.), 1993, 62,
839.
Key Words:
Alkylation of carbonyl compounds through conversion into oxycyclopropane
intermediates.
O. G. Kulinkovich, Pol. J. Chem., 1997, 71, 849.
Key Words:
carbonyl compounds/alkylation/cyclopropanol derivatives/ring opening/SILYL
ENOL ETHERS/ALPHA-METHYLENE KETONES/BOND-FORMING REACTIONS/ONE-POT SYNTHESIS/ORGANIC-SYNTHESIS/DIASTEREOSELECTIVE
SYNTHESIS/CARBOXYLIC ESTERS/ACID-CHLORIDES/1-SUBSTITUTED CYCLOPROPANOLS/SUBSTITUTED
CYCLOPROPANES
Titanacyclopropanes as versatile intermediates for carbon-carbon bond
formation in reactions with unsaturated compounds.
O. G. Kulinkovich, Pure Appl. Chem., 2000, 72, 1715.
Key Words:
HALIDES/ESTERS
1,n-dicarbanionic titanium intermediates from monocarbanionic organometallics
and their application in organic synthesis.
O. G. Kulinkovich, A. deMeijere, Chem. Rev., 2000, 100,
2789.
Key Words:
LOW-VALENT-TITANIUM/NUCLEOPHILIC ACYL SUBSTITUTION/MEDIATED CARBONYL
OLEFINATIONS/HIGHLY EFFICIENT SYNTHESIS/RAY CRYSTAL-STRUCTURE/TITANOCENE
VINYLIDENE COMPLEXES/ISOPROPOXIDE-CATALYZED REACTION/TRANSITION-METAL COMPLEXES/OPTICALLY-ACTIVE
COMPLEXES/I-PRMGCL REAGENT