Bimetallic Catalytic Systems Containing Titanium, Zirconium, Nickel, And
Palladium. Their Application to Selective Organic Synthesis.
E. Negishi, Pure Appl. Chem., 1981, 53, 2333.
Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ALKENES/ORGANOMETALLICS/TITANIUM/ZIRCONIUM/NICKEL/PALLADIUM/C-M/Ti/Zr/Ni/Pd/CARBOMETALLATION/Al/COUPLING/C=C-C=C/E,Z/C=C-C=C/E,E/C=C-M/Al/C=C-C-C-X/OH/C=C-X/Br/I/C=C-C-X/OH
E. Negishi, in Comprehensive Organometallic Chemistry, Vol. 7 (Eds.: G.
Wilkinson, F. G. A. Stone, E. Abel), Pergamon, Oxford, 1982, pp. 255.
Key Words:
ORGANOMETALLICS/BORON/C=C-M/B/Ar-M/B/C-M/B
Controlled Carbometallation as a Tool for Carbon-Carbon Bond Formation and
its Application to Cyclisation.
E. Negishi, Acc. Chem. Res., 1987, 20, 65.
Key Words:
ORGANOMETALLICS/ZIRCONIUM/C-X/Zr/ANNULATION CARBOMETALLATION
E. Negishi, in Advances in Metal-Organic Chemistry, Vol. 1 (Ed.: L. S.
Liebeskind), Jai Press, Inc., Greenwich, CT, 1989.
Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ALKENES/ORGANOMETALLICS/ELEMENT/NICKEL/PALLADIUM/Ni/Pd
Cyclization, coupling, and rearrangement reactions of organozirconium and
related compoumds.
E. Negishi, Chem. Scr., 1989, 29, 457.
Key Words:
ORGANOMETALLICS/ZIRCONIUM/Zr
E. Negishi, in Comprehensive Organic Synthesis, Vol. 5 (Eds.: B. M.
Trost, I. Fleming), Pergamon Press, Oxford, 1991, p. 1163.
Key Words:
ORGANOMETALLICS/ZIRCONIUM/C-C BOND FORMATION/ANNULATION/5-RING/Zr
Zipper-mode cascade carbometalation for construction of polycyclic structures.
E. Negishi, Pure Appl. Chem., 1992, 64, 323.
Key Words:
Recent advances in the chemistry of zirconocene and related compounds.
E. Negishi, Ed., Tetrahedron Symposium-in-Print, 1995, 51,
4255.
Key Words:
Zr/ZIRCONIUM
Novel and selective alpha-substitution of ketones and other carbonyl
compounds based on Pd-catalyzed cross coupling of alpha,beta-unsaturated
carbonyl derivatives containing alpha-halogen or alpha-metal groups.
E. Negishi, J. Organomet. Chem., 1999, 576, 179.
Key Words:
alpha-substitution of carbonyl compounds/Pd-catalyzed cross coupling/alpha-halo-alpha,beta-unsaturated
carbonyl compounds/alpha-metallo-alpha,beta-unsaturated carbonyl compounds/BETA-DICARBONYL
COMPOUNDS/SILYL ENOL ETHERS/REFORMATSKY REAGENT/BOND FORMATION/ALK-1-ENYL-LEAD
TRIACETATES/CEPHALOSPORIN CHEMISTRY/ZEROVALENT COMPLEXES/PALLADIUM CATALYSIS/ORGANOTIN
COMPOUNDS/ALKENYL HALIDES
Principle of activation of electrophiles by electrophiles through dimeric
association - Two are better than one.
E. Negishi, Chem. Eur. J., 1999, 5, 411.
Key Words:
aluminum/dimerization/electron deficiency/Lewis acids/zirconium/TRANSITION-METAL
CATALYSIS/CARBON BOND FORMATION/BRIDGED TETRAHYDROINDENYL LIGANDS/ANSA-METALLOCENE
DERIVATIVES/CP2ZR(H)CL SCHWARTZ REAGENT/CONTROLLED CARBOMETALATION/ORGANOZIRCONIUM
COMPOUNDS/CASCADE CARBOALUMINATION/MONOSUBSTITUTED ALKENES/TITANOCENE
DERIVATIVES
Some newer aspects of organozirconium chemistry of relevance to organic
synthesis. Zr-Catalyzed enantioselective carbometallation.
E. Negishi, Pure Appl. Chem., 2001, 73, 239.
Key Words:
TRANSITION-METAL CATALYSIS; CARBON BOND FORMATION; CONTROLLED
CARBOMETALATION; MONOSUBSTITUTED ALKENES; CONVENIENT PROCEDURE; ZIRCONIUM;
ZIRCONOCENE; HYDROZIRCONATION; REAGENTS; ALKYNES
Thexylborane - A Highly Versatile Reagent for Organic Synthesis via
Hydroboration.
E. Negishi, H. C. Brown, Synthesis, 1974, 77.
Key Words:
REAGENTS/C-M/B/THEXYLBORANE/C=C/ALKENES/C=C-C=C/DIENES/ACIDS/O=C-OH/HYDROMETALLATION/HYDROBORATION/REDUCTION/C-X/OH/ALKOHOLS/O=C-H/KETONES/ALDEHYDES
E. Negishi, D. Choueiry, in Preparation of Alkenes. A Practical Approach
(Eds.: J. M. J. Williams, C. J. Moody), Oxford University Press, Oxford, U. K., 1996,
pp. 137.
Key Words:
Zirconium-catalyzed enantioselective carboalumination of ''unactivated''
alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation
E. Negishi, S. Q. Huo, Pure Appl. Chem., 2002, 74, 151.
Key Words:
CONTROLLED CARBOMETALATION/MONOSUBSTITUTED ALKENES/METAL CATALYSIS/ZIRCONOCENE/POLYMERIZATION/DERIVATIVES/COMPLEXES/REAGENTS/ALKYNES/METHYLALUMINATION
Formation of Carbon-Carbon and Carbon-Heteroatom Bonds via Organoboranes and
Organoborates.
E. Negishi, M. J. Idacavage, Org. React. (N.Y.), 1985, 33,
1.
Key Words:
ORGANOMETALLICS/BORON/B
An odyssey from stoichiometric carbotitanation of alkynes to
zirconium-catalysed enantioselective carboalumination of alkenes.
E. Negishi, D. Y. Kondakov, Chem. Soc. Rev., 1996, 25, 417.
Key Words:
METAL-PROMOTED CYCLIZATION/CARBON BOND FORMATION/CONTROLLED CARBOMETALATION/CONVENIENT
PROCEDURE/ORGANOZIRCONIUM COMPOUNDS/ZIRCONOCENE DERIVATIVES/MONOSUBSTITUTED
ALKENES/HYDROGEN ABSTRACTION/GRIGNARD-REAGENTS/COMPLEXES
Regio- and stereoselective synthesis of gamma-alkylidenebutenolides and
related compounds.
E. Negishi, M. Kotora, Tetrahedron, 1997, 53, 6707.
Key Words:
PALLADIUM-CATALYZED CARBONYLATION/METAL-PROMOTED CYCLIZATION/ENOL-LACTONES/GONIOBUTENOLIDE-A/ALKYNOIC
ACIDS/UNSATURATED LACTONES/CONVENIENT SYNTHESIS/ACETYLENIC-COMPOUNDS/ALKYLIDENE
LACTONES/EFFICIENT SYNTHESIS
E. Negishi, F. Liu, in Metal-Catalyzed Cross-Coupling Reactions (Eds.: F.
Diederich, P. J. Stang), Wiley-VCH, Inc, 605 Third Ave/New York/NY 10158-0012, 1998,
pp. 1.
Key Words:
E. Negishi, J. L. Montchamp, in Metallocenes: Synthesis, Reactivity,
Applications, Vol. 1 and 2 (Eds.: A. Togni, R. L. Halterman), Wiley-Vch, Inc,
605 Third Ave, New York, NY 10158-0012, USA, 1998, pp. 241.
Key Words:
Organozirconium Compounds as New Reagents and Intermediates.
E. Negishi, T. Takahashi, Aldrichimica Acta, 1985, 18, 31.
Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/HETEROALKENES/ORGANOMETALLICS/ZIRCONIUM/C-C
BOND FORMATION/ANNULATIONS/4-RING/5-RING/ALKENES/C-M/Zr/HYDROMETALLATION/Zr/CARBOMETALLATION/Zr/CARBOMETALLATION/Al/HALOGENOLYSIS/TRANSMETALLATION/CARBONYLATION/COUPLING
Organozirconium Compounds in Organic Synthesis.
E. Negishi, T. Takahashi, Synthesis, 1988, 1.
Key Words:
ORGANOMETALLICS/ZIRCONIUM/Zr
E. Negishi, T. Takahashi, in Reviews on Heteroatom Chemistry, Vol. 6
(Ed.: S. Oae), MYU K.K., Tokyo, Japan, 1992.
Key Words:
Zr
Palladium- or Nickel-Catalysed Cross Coupling. A New Selective Method for C-C
Bond Formation.
E.-i. Negishi, Acc. Chem. Res., 1982, 15, 340.
Key Words:
ORGANOMETALLICS/NICKEL/PALLADIUM/COUPLING/ALKENES/ALKANES/Ni/Pd
Cyclic carbopalladation. A versatile synthetic methodology for the
construction of cyclic organic compounds.
E. I. Negishi, C. Coperet, S. M. Ma, S. Y. Liou, F. Liu, Chem. Rev., 1996,
96, 365.
Key Words:
CATALYTIC ASYMMETRIC-SYNTHESIS/METAL-PROMOTED CYCLIZATION/ANION CAPTURE
PROCESSES/INTRAMOLECULAR HECK REACTIONS/MEDIATED TETRAENE CARBOCYCLIZATIONS/QUATERNARY
CARBON CENTERS/STEREOSPECIFIC GROUP TRANSFER/NATURAL PRODUCT SYNTHESIS/CIS-DECALIN
DERIVATIVES/POLYFUSED RING-SYSTEMS
E.-i. Negishi, D. Choueiry, in Comprehensive Organic Functional Group
Transformations, Vol. 2 (Eds.: A. R. Katritzky, O. Meth-Cohn, C. W. Rees),
Elsevier Science, Oxford, U.K., 1995, pp. 951.
Key Words:
E.-i. Negishi, T. Takahashi, in Organometallics: Compounds of Groups 7-3 (Mn···,
Cr···, V···, Ti···, Sc···, La···, Ac···, Vol. 2 (Ed.: T.
Imamoto), Georg Thieme Verlag, Stuttgart - New York, 2002, pp. 681.
Key Words:
Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and
Related Complexes of Synthetic Interest.
E.-I. Negishi, T. Takahashi, Acc. Chem. Res., 1994, 27,
124.
Key Words:
Zr