The Ramberg-Backlund Rearrangement.

L. A. Paquette, Org. React. (N.Y.), 1977, 25, 1.

Key Words:
NAME REACTIONS/C-X(Y)/Br(SO2)/C-X(Y)/Cl(SO2)/SULFONES/EXTRUSION/CHELOTROPIC REACTION/RAMBERG-BACKLUND REARRANGEMENT/ALKENES/C=C/S



Recent Developments in Polycyclopentanoid Chemistry.

L. A. Paquette, Ed., Tetrahedron Symposium-in-Print, 1981, 37, 4357.

Key Words:
C-C BOND FORMATION/ANNULATIONS/5-RING



L. A. Paquette, in Asymmetric Synthesis. Stereodifferentiating Reactions, Part B., Vol. 3 (Ed.: J. D. Morrison), AP, New York, 1984, p. 455.

Key Words:
C-C BOND FORMATION/PERICYCLIC REACTIONS/CYCLOADDITIONS/[4+2]/[3+2]/[2+2]/STEREOSELECTIVE/ALKENES/DIENES/C=C/C=C-C=C/ANNULATION/6-RING ANNULATION/5-RING/ANNULATION/4-RING



L. A. Paquette, in Strategies and Tactics in Organic Synthesis, Vol. 1 (Ed.: T. Lindberg), Academic Press, 1984.

Key Words:



Synthetic Routes to Cyclopentanoid-Fused Unnatural and Natural Products.

L. A. Paquette, Aldrichimica Acta, 1984, 17, 43.

Key Words:
TARGET SYNTHESIS/TERPENOIDS/UNNATURAL PRODUCTS/C-C BOND FORMATION/ANNULATIONS/5-RING/CARBRING/5/CYCLOPENTANES/NATURAL PRODUCTS



Silyl-Substituted Cyclopropanes as Versatile Synthetic Reagents.

L. A. Paquette, Chem. Rev., 1986, 86, 733.

Key Words:
C-C BOND FORMATION/ANNULATIONS/3-RING/Si



Dodecahedranes and Allied Spherical Molecules.

L. A. Paquette, Chem. Rev., 1989, 89, 1051.

Key Words:
TARGET SYNTHESIS/UNNATURAL PRODUCTS/ANNULATION/5-RING/RING CONTRACTION/6 TO 5/DODECAHEDRANES



Stereocontrolled construction of complex cyclic ketones by oxy-Cope rearrangement.

L. A. Paquette, Angew. Chem., Int. Ed. Engl., 1990, 29, 609.

Key Words:
C-C BOND FORMATION/PERICYCLIC REACTIONS/SIGMATROPIC/[3,3]/ANNULATION/MEDIUM RING/RING CONTRACTION/N TO M



Carbonyl Group Regeneration with Substantive Enhancement of Structural Complexity.

L. A. Paquette, Synlett, 1990, 67.

Key Words:



L. A. Paquette, in Advances in Theoretically Interesting Molecules, Vol. 2 (Ed.: R. P. Thummel), Jai Press Inc, Greenwich, CT, 1992, pp. 1.

Key Words:



L. A. Paquette, in Studies in Natural Products Chemistry, Vol. 11 (Ed.: A. Rahman), Elsevier Science Publ B V, Amsterdam, Netherlands, 1992, pp. 3.

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Investigations into furanocembranolide diterpene construction. Total synthesis of dihydropseudopterolide, gorgiacerone, and acerosolide. Reversible interconversion of pseudopterolide and tobagolide.

L. A. Paquette, Chemtracts: Organic Chemistry, 1992, 5, 141.

Key Words:



L. A. Paquette, in Studies in Natural Products Chemistry, Vol 13 : Bioactive Natural Products Pt A (Eds.: Atta-ur-rahman, F. Z. Basha), Elsevier Science Publ B V, Amsterdam, Netherlands, 1993, pp. 3.

Key Words:



Centenary lecture. Bridgehead unsaturation in compounds of nature: A proper forum for unleashing the potential of organic synthesis.

L. A. Paquette, Chem. Soc. Rev., 1995, 24, 9.

Key Words:
OXY-COPE REARRANGEMENT/CERORUBENIC ACID-III/STEREOCONTROLLED CONSTRUCTION/ENANTIOSELECTIVE APPROACH/CLEOME-VISCOSA/TAXOL/SUBSTITUENT/SIGMATROPY/SYSTEM/EREMANTHOLIDES



Recent applications of anionic oxy-Cope rearrangements.

L. A. Paquette, Tetrahedron, 1997, 53, 13971.

Key Words:
CERORUBENIC ACID-III/BASE-CATALYZED REARRANGEMENT/CHIRAL CYCLOPENTENYL ORGANOMETALLICS/VINYL TERTIARY-ALCOHOLS/BIS-ALLYLIC ETHERS/AB RING-SYSTEM/STEREOCONTROLLED CONSTRUCTION/SQUARATE ESTERS/SIGMATROPIC REARRANGEMENT/STEREOSELECTIVE SYNTHESIS



L. A. Paquette, in Recent Research Developments in Chemical Sciences, Vol. 1 (Ed.: S. G. Pandalai), Transworld Research Network, Tc 36/248 1/Trivandrum 695008/India, 1997, pp. 1.

Key Words:



Cascade rearrangements following twofold addition of alkenyl anions to squarate esters.

L. A. Paquette, Eur. J. Org. Chem., 1998, 1709.

Key Words:
4 pi conrotatory ring openings/8 pi conrotatory cyclizations/octatetraene helical equilibration/dianionic oxy-Cope rearrangements/1,2-dioxidocyclobutenes/CONROTATORY ELECTROCYCLIC REACTIONS/OCTATETRAENE INTERMEDIATE/HELICAL EQUILIBRATION/COPE REARRANGEMENT/SYNTHETIC UTILITY/2-FOLD ADDITION/VINYL ANIONS/RING-SYSTEM/ROUTE/CYCLOBUTENES



The electrophilic and radical behavior of alpha-halosulfonyl systems.

L. A. Paquette, Synlett, 2001, 1.

Key Words:
nucleophilic displacement; field effects; intramolecular eliminations; electrophilic radicals; sulfones; sulfonamides; USEFUL ETHYLENEDIIDE EQUIVALENTS; NUCLEOPHILIC DISPLACEMENTS; HALOGEN ATOMS; HALOALKANESULFONYL BROMIDES; INTRAMOLECULAR CYCLIZATION; SULFONYL RADICALS; BETA-KETOSULFONES; ORGANIC-SYNTHESIS; MICHAEL ADDITION; EXO-GLYCALS



The development of strategies for the elaboration of linear triquinane sesquiterpenoids: Hypnophilin and ceratopicanol as exemplary case studies

L. A. Paquette, Curr. Org. Chem., 2002, 6, 1045.

Key Words:
olefin cyclo-additions/squarate esters/organic-synthesis/chemistry/(+/-)-ceratopicanol/stereochemistry/alcohols/iridoids/rearrangement/polyquinanes



New transformations involving squarate esters. Multi-channel rearrangement options available to 2-(dimethoxy-methyl)-1-cycloalken-1-yl adducts.

L. A. Paquette, P. Doussot, Research on Chemical Intermediates, 1996, 22, 767.

Key Words:
REGIOSPECIFIC SYNTHESIS/THERMAL REARRANGEMENT/RING-EXPANSION/REGIOCONTROLLED CONSTRUCTION/SUBSTITUTED QUINONES/DIMETHYL SQUARATE/VINYL ANION/CYCLOBUTENONES/ACID/(+/-)-FREDERICAMYCIN-A



The need for an incisive analysis of the regioselectivity associated with the deprotonation of alpha-alkoxy and alpha-acyloxy ketones.

L. A. Paquette, S. V. ONeil, N. Guillo, Q. B. Zeng, D. G. Young, Synlett, 1999, 1857.

Key Words:
aldol reactions/alkylations/ethers/ketones/regioselectivity/PI-FACE SELECTIVITY/HIGH DIASTEREOFACIAL SELECTIVITIES/ASYMMETRIC ALDOL REACTIONS/HYDROXY CARBOXYLIC-ACIDS/ACYCLIC STEREOSELECTION/DICYCLOHEXYLCHLOROBORANE TRIETHYLAMINE/STEREOCONTROLLED SYNTHESIS/POLYPROPIONATE SYNTHESIS/DIALKYLBORON CHLORIDES/ALLYLOXY CARBANIONS



The intramolecular SN' reaction.

L. A. Paquette, C. J. M. Stirling, Tetrahedron, 1992, 48, 7383.

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From D-camphor to the taxanes. Highly concise rearrangement-based approaches to taxusin and taxol.

L. A. Paquette, M. Z. Zhao, F. Montgomery, Q. B. Zeng, T. Z. Wang, S. Elmore, K. Combrink, H. L. Wang, S. Bailey, Z. A. Su, Pure Appl. Chem., 1998, 70, 1449.

Key Words:
C-RING/STEREOCONTROLLED SYNTHESIS/COPE REARRANGEMENT/OXIDATION LEVEL/PINENE PATH/A-RING/CONSTRUCTION/FUNCTIONALIZATION/OXYGENATION/PRECURSORS