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A novel approach to dihydropyrrolones from iron-substituted alpha,beta-unsaturated imines and organolithium and Grignard reagents: Developments, mechanisms and stereoselective syntheses.

K. RuckBraun, P. Amrhein, Eur. J. Org. Chem., 2000, 3961.

Key Words:
carbonylations/Grignard reactions/iron/lactams/lithium/Schiff bases/N-sulfinylimines/THIOOXIME S-OXIDES/BENZYLIDENE-P-TOLUENESULFINAMIDES/ALPHA-AMINO-ACIDS/N-SULFONYL IMINES/ASYMMETRIC-SYNTHESIS/ORGANOMETALLIC REAGENTS/ORGANIC-SYNTHESIS/GAMMA-LACTAMS/NITROGEN-HETEROCYCLES/ADDITION-REACTIONS



Catalytic Asymmetric Synthesis Using Rare Earth-Derived Heterobimetallic BINOL Complexes.

K. Ruck-Braun, H. Kunz, Chemtracts: Organic Chemistry, 1998, 11, 264.

Key Words:
Asymmetric synthesis/BINOL catalyst Catalysts/rare earth BINOL complex



K. Rück-Braun, H. Kunz, Chiral Auxiliaries in Cycloadditions., Wiley, New York, 1999.

Key Words:
Cycloadditions/chiral auxiliaries/book



Organoiron compounds for selective organic transformations.

K. RuckBraun, M. Mikulas, P. Amrhein, Synthesis, 1999, 727.

Key Words:
iron/[3+2] cycloadditions/carbonylations/cyclopropanations/catalysis/IRON LEWIS-ACID/ALPHA,BETA-UNSATURATED ACYLIRON COMPLEXES/ASSISTED CYCLO-ADDITIONS/ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL COMPLEXES/ELECTRON-DEFICIENT OLEFINS/METHYLENE TRANSFER REAGENT/METAL CARBENE COMPLEXES/BOND-CLEAVING REACTIONS/DIELS-ALDER REACTIONS/H INSERTION REACTIONS