A novel approach to dihydropyrrolones from iron-substituted
alpha,beta-unsaturated imines and organolithium and Grignard reagents:
Developments, mechanisms and stereoselective syntheses.
K. RuckBraun, P. Amrhein, Eur. J. Org. Chem., 2000, 3961.
Key Words:
carbonylations/Grignard reactions/iron/lactams/lithium/Schiff bases/N-sulfinylimines/THIOOXIME
S-OXIDES/BENZYLIDENE-P-TOLUENESULFINAMIDES/ALPHA-AMINO-ACIDS/N-SULFONYL IMINES/ASYMMETRIC-SYNTHESIS/ORGANOMETALLIC
REAGENTS/ORGANIC-SYNTHESIS/GAMMA-LACTAMS/NITROGEN-HETEROCYCLES/ADDITION-REACTIONS
Catalytic Asymmetric Synthesis Using Rare Earth-Derived Heterobimetallic
BINOL Complexes.
K. Ruck-Braun, H. Kunz, Chemtracts: Organic Chemistry, 1998, 11,
264.
Key Words:
Asymmetric synthesis/BINOL catalyst Catalysts/rare earth BINOL complex
K. Rück-Braun, H. Kunz, Chiral Auxiliaries in Cycloadditions., Wiley,
New York, 1999.
Key Words:
Cycloadditions/chiral auxiliaries/book
Organoiron compounds for selective organic transformations.
K. RuckBraun, M. Mikulas, P. Amrhein, Synthesis, 1999, 727.
Key Words:
iron/[3+2] cycloadditions/carbonylations/cyclopropanations/catalysis/IRON
LEWIS-ACID/ALPHA,BETA-UNSATURATED ACYLIRON COMPLEXES/ASSISTED CYCLO-ADDITIONS/ALLYL(CYCLOPENTADIENYL)IRON(II)
DICARBONYL COMPLEXES/ELECTRON-DEFICIENT OLEFINS/METHYLENE TRANSFER REAGENT/METAL
CARBENE COMPLEXES/BOND-CLEAVING REACTIONS/DIELS-ALDER REACTIONS/H INSERTION
REACTIONS