Radical carboxylations of iodoalkanes and saturated alcohols using carbon monoxide.

I. Ryu, Chem. Soc. Rev., 2001, 30, 16.

Key Words:
COMPLEX CATALYZED CARBONYLATION; ACYL RADICALS; ADDITION-REACTIONS; ALKOXYL RADICALS; ORGANIC IODIDES; BETA-HYDROGENS; DELTA-LACTONES; ALKYL IODIDES; ALKENES; ATOM



Free-radical carbonylations: Then and now.

I. Ryu, N. Sonoda, Angew. Chem., Int. Ed. Engl., 1996, 35, 1051.

Key Words:
CARBON-CARBON COUPLING/CARBON MONOXIDE/CARBONYLATION/RADICALS/SYNTHETIC METHODS/ALKENE ADDITION-REACTIONS/ABSOLUTE RATE CONSTANTS/BOND-FORMING REACTIONS/COMPLEX CATALYZED CARBONYLATION/ELECTRON-SPIN-RESONANCE/TERTIARY ALKYL RADICALS/NORMAL-BUTYLTIN HYDRIDE/C-H ACTIVATION/CARBON-MONOXIDE/ORGANIC-SYNTHESIS



Tandem radical reactions of carbon monoxide, isonitriles, and other reagent equivalents of the geminal radical acceptor radical precursor synthon.

I. Ryu, N. Sonoda, D. P. Curran, Chem. Rev., 1996, 96, 177.

Key Words:
ABSOLUTE RATE CONSTANTS/BOND-FORMING REACTIONS/N-AZIRIDINYL IMINES/CYCLIZATION REACTIONS/ADDITION-REACTIONS/IMIDOYL RADICALS/ATOM TRANSFER/ARYLIMIDOYL RADICALS/AROMATIC ANNELATION/ALKYL RADICALS