The Preparation of Grignard Reagents via the Hydromagnesiation Reaction, and their Use in Organic Synthesis.

F. Sato, J. Organomet. Chem., 1985, 285, 53.

Key Words:
ORGANOMETALLICS/MAGNESIUM/HYDROMETALLATION/Mg/HYDROMAGNESIATION



Synthesis of enantiomerically pure secondary gamma-halo allylic alcohols and their use in the synthesis of leukotrienes.

F. Sato, Y. Kobayashi, Synlett, 1992, 849.

Key Words:



The divalent titanium complex Ti(O-i-Pr)4/2 i-PrMgX as an efficient and practical reagent for fine chemical synthesis.

F. Sato, S. Okamoto, Adv. Synth. Catal., 2001, 343, 759.

Key Words:



Bicyclization of dienes, enynes, and diynes with Ti(II) reagent. New developments towards asymmetric synthesis.

F. Sato, H. Urabe, S. Okamoto, Pure Appl. Chem., 1999, 71, 1511.

Key Words:
INTRAMOLECULAR CYCLIZATION/DIASTEREOSELECTIVE SYNTHESIS/ETHYLMAGNESIUM BROMIDE/FACILE CONSTRUCTION/ALKYNE COMPLEXES/ESTERS/(ETA(2)-PROPENE)TI(O-I-PR)(2)/CYCLOPROPANOLS/GENERATION/TITANABICYCLES



Synthesis of organotitanium complexes from alkenes and alkynes and their synthetic applications.

F. Sato, H. Urabe, S. Okamoto, Chem. Rev., 2000, 100, 2835.

Key Words:
NUCLEOPHILIC ACYL SUBSTITUTION/TITANIUM ARYLOXIDE COMPOUNDS/ONE-POT SYNTHESIS/EARLY-TRANSITION-METAL/OPTICALLY-ACTIVE 5-(TERT-BUTYLDIMETHYLSILOXY)-2-CYCLOHEXENONE/STEREOSELECTIVE COUPLING REACTIONS/PROPARGYLIC ALCOHOL DERIVATIVES/ISOPROPOXIDE-CATALYZED REACTION/ALLYLIC TITANOCENE DERIVATIVES/TITANIUM(II)-BASED Z-REDUCTION



Synthetic reactions mediated by a Ti(O-i-Pr)(4)/2 i-PrMgX reagent.

F. Sato, H. Urabe, S. Okamoto, Synlett, 2000, 753.

Key Words:
NUCLEOPHILIC ACYL SUBSTITUTION/HIGHLY EFFICIENT SYNTHESIS/ONE-POT SYNTHESIS/OPTICALLY-ACTIVE 5-(TERT-BUTYLDIMETHYLSILOXY)-2-CYCLOHEXENONE/PROPARGYLIC ALCOHOL DERIVATIVES/TITANIUM(II)-BASED Z-REDUCTION/TITANIUM-ALKYNE COMPLEXES/CHIRAL BUILDING-BLOCKS/CARBONYL-COMPOUNDS/DIASTEREOSELECTIVE SYNTHESIS