Methods and Possibilities of Nucleophilic Acylation.
D. Seebach, Angew. Chem., Int. Ed. Engl., 1969, 8, 639.
Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/ACYLATION/1,3-DITHIANE/C=C-X-M/O-Li/C-X(Y)/S(S)/C-M(X)(Y)/Li(S)(S)/NUCLEOPHILIC
ACYLATION/S
Methods of Reactivity Umpolung.
D. Seebach, Angew. Chem., Int. Ed. Engl., 1979, 18, 239.
Key Words:
ODDS AND ENDS/STRATEGIES AND THEORY OF SYNTHESIS/UMPOLUNG
D. Seebach, in Modern Synthetic Methods, Vol. 2 (Ed.: R. Scheffold), Otto
Salle Verlag, Frankfurt/Main, 1980, pp. 91.
Key Words:
Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective
C-Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex
Structures.
D. Seebach, Angew. Chem., Int. Ed. Engl., 1988, 27, 1624.
Key Words:
C-C BOND FORMATION/APPENDAGES/ENOLATES/C=C-X-M/O-Li/ALKYLATION/Li
From synthetic methods to .gamma.-peptides - from chemistry to biology.
D. Seebach, A. K. Beck, M. Brenner, C. Gaul, A. Heckel, Chimia, 2001,
55, 831.
Key Words:
review synthetic methodol shift biol
Reduction of ketones with LiAlH4 complexes of alpha,alpha,alpha',alpha'-tetraaryl-1,3-dioxolane-4,5-dimethanols
(TADDOLs) - A combination of enantioselective reduction and clathrate formation
with a discussion of LAH reagents bearing C-2-symmetrical ligands.
D. Seebach, A. K. Beck, R. Dahinden, M. Hoffmann, F. N. M. Kuhnle, Croatica
Chemica Acta, 1996, 69, 459.
Key Words:
LITHIUM ALUMINUM-HYDRIDE/AXIALLY DISSYMMETRIC MOLECULES/HIGH ENANTIOMERIC
PURITY/DIELS-ALDER REACTIONS/CHIRAL MEDIUM DDB/ASYMMETRIC REDUCTION/TARTARIC
ACID/PROCHIRAL KETONES/AROMATIC KETONES/REDUCING AGENT
TADDOLs, their derivatives, and TADDOL analogues: Versatile chiral
auxiliaries.
D. Seebach, A. K. Beck, A. Heckel, Angew. Chem., Int. Ed. Engl., 2001,
40, 92.
Key Words:
asymmetric catalysis; asymmetric synthesis; enantiomer separation; TADDOL;
OPTICALLY-ACTIVE HOST; DIELS-ALDER REACTION; HELICAL TWISTING POWER; CATALYTIC
ENANTIOSELECTIVE ADDITION; 1,3-DIPOLAR CYCLOADDITION REACTIONS;
BINAPHTHOL-TITANIUM COMPLEX; TRANSITION-METAL COMPLEXES; BETA-AMINO ALCOHOLS;
SILYL ENOL ETHERS; EXPERIMENTAL-DESIGN METHODOLOGY
Excursions of synthetic organic chemists to the World of oligomers and
polymers.
D. Seebach, A. K. Beck, M. Rueping, J. V. Schreiber, H. Sellner, Chimia, 2001,
55, 98.
Key Words:
review oligomer polymer synthesis/styrene polymn dendritic crosslinking
review/hydroxybutanoic acid polymn review/amino acid peptide oligomer review
Umpolung of Amine Reactivity. Nucleophilic alpha-(Secondary Amino)Alkylation
via Metalated Nitrosamines.
D. Seebach, D. Enders, Angew. Chem., Int. Ed. Engl., 1975, 14,
15.
Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/N=C-C-M/Li/C=C-X-M/N-Li
D. Seebach, R. Imwinkelkried, T. Weber, in Modern Synthetic Methods, Vol. 4
(Ed.: R. Scheffold), Springer, Berlin, 1986, p. 125.
Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/ACETALS/ENAMINES/ENANTIOSELECTIVE
beta-Peptides: a surprise at every turn.
D. Seebach, J. L. Matthews, J. Chem. Soc., Chem. Commun., 1997,
2015.
Key Words:
ACID/DERIVATIVES/ALKYLATION/NANOTUBES
The Unambiguous Specification of the Steric Course of Asymmetric Syntheses.
D. Seebach, V. Prelog, Angew. Chem., Int. Ed. Engl., 1982, 21,
654.
Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/PHYSICAL ORGANIC/STEREOCHEMISTRY
Self-regeneration of stereocenters (SRS) - Applications, limitations, and
abandonment of a synthetic principle.
D. Seebach, A. R. Sting, M. Hoffmann, Angew. Chem., Int. Ed. Engl., 1996,
35, 2708.
Key Words:
ASYMMETRIC SYNTHESES/CHIRAL SYNTHETIC BUILDING BLOCKS/ENOLATES LITHIUM
COMPOUNDS/ALPHA-AMINO-ACIDS/DIELS-ALDER REACTIONS/CHIRAL BUILDING-BLOCKS/ENANTIOMERICALLY
PURE DIHYDROPYRIMIDINONES/RAY CRYSTAL-STRUCTURE/EFFICIENT ENANTIOSELECTIVE
SYNTHESIS/DIASTEREOSELECTIVE RADICAL-ADDITION/HETEROSUBSTITUTED CARBOXYLIC-ACIDS/STEREOSELECTIVE
ALDOL REACTIONS/PIVALALDEHYDE N,N-ACETAL CENTER
D. Seebach, B. Weidmann, L. Widler, in Modern Synthetic Methods, Vol. 3
(Ed.: R. Scheffold), Springer, Berlin, 1983, p. 217.
Key Words:
ORGANOMETALLICS/TITANIUM/ZIRCONIUM/Ti/Zr