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Methods and Possibilities of Nucleophilic Acylation.

D. Seebach, Angew. Chem., Int. Ed. Engl., 1969, 8, 639.

Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/ACYLATION/1,3-DITHIANE/C=C-X-M/O-Li/C-X(Y)/S(S)/C-M(X)(Y)/Li(S)(S)/NUCLEOPHILIC ACYLATION/S



Methods of Reactivity Umpolung.

D. Seebach, Angew. Chem., Int. Ed. Engl., 1979, 18, 239.

Key Words:
ODDS AND ENDS/STRATEGIES AND THEORY OF SYNTHESIS/UMPOLUNG



D. Seebach, in Modern Synthetic Methods, Vol. 2 (Ed.: R. Scheffold), Otto Salle Verlag, Frankfurt/Main, 1980, pp. 91.

Key Words:



Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective C-Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex Structures.

D. Seebach, Angew. Chem., Int. Ed. Engl., 1988, 27, 1624.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENOLATES/C=C-X-M/O-Li/ALKYLATION/Li



From synthetic methods to .gamma.-peptides - from chemistry to biology.

D. Seebach, A. K. Beck, M. Brenner, C. Gaul, A. Heckel, Chimia, 2001, 55, 831.

Key Words:
review synthetic methodol shift biol



Reduction of ketones with LiAlH4 complexes of alpha,alpha,alpha',alpha'-tetraaryl-1,3-dioxolane-4,5-dimethanols (TADDOLs) - A combination of enantioselective reduction and clathrate formation with a discussion of LAH reagents bearing C-2-symmetrical ligands.

D. Seebach, A. K. Beck, R. Dahinden, M. Hoffmann, F. N. M. Kuhnle, Croatica Chemica Acta, 1996, 69, 459.

Key Words:
LITHIUM ALUMINUM-HYDRIDE/AXIALLY DISSYMMETRIC MOLECULES/HIGH ENANTIOMERIC PURITY/DIELS-ALDER REACTIONS/CHIRAL MEDIUM DDB/ASYMMETRIC REDUCTION/TARTARIC ACID/PROCHIRAL KETONES/AROMATIC KETONES/REDUCING AGENT



TADDOLs, their derivatives, and TADDOL analogues: Versatile chiral auxiliaries.

D. Seebach, A. K. Beck, A. Heckel, Angew. Chem., Int. Ed. Engl., 2001, 40, 92.

Key Words:
asymmetric catalysis; asymmetric synthesis; enantiomer separation; TADDOL; OPTICALLY-ACTIVE HOST; DIELS-ALDER REACTION; HELICAL TWISTING POWER; CATALYTIC ENANTIOSELECTIVE ADDITION; 1,3-DIPOLAR CYCLOADDITION REACTIONS; BINAPHTHOL-TITANIUM COMPLEX; TRANSITION-METAL COMPLEXES; BETA-AMINO ALCOHOLS; SILYL ENOL ETHERS; EXPERIMENTAL-DESIGN METHODOLOGY



Excursions of synthetic organic chemists to the World of oligomers and polymers.

D. Seebach, A. K. Beck, M. Rueping, J. V. Schreiber, H. Sellner, Chimia, 2001, 55, 98.

Key Words:
review oligomer polymer synthesis/styrene polymn dendritic crosslinking review/hydroxybutanoic acid polymn review/amino acid peptide oligomer review



Umpolung of Amine Reactivity. Nucleophilic alpha-(Secondary Amino)Alkylation via Metalated Nitrosamines.

D. Seebach, D. Enders, Angew. Chem., Int. Ed. Engl., 1975, 14, 15.

Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/N=C-C-M/Li/C=C-X-M/N-Li



D. Seebach, R. Imwinkelkried, T. Weber, in Modern Synthetic Methods, Vol. 4 (Ed.: R. Scheffold), Springer, Berlin, 1986, p. 125.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/ACETALS/ENAMINES/ENANTIOSELECTIVE



beta-Peptides: a surprise at every turn.

D. Seebach, J. L. Matthews, J. Chem. Soc., Chem. Commun., 1997, 2015.

Key Words:
ACID/DERIVATIVES/ALKYLATION/NANOTUBES



The Unambiguous Specification of the Steric Course of Asymmetric Syntheses.

D. Seebach, V. Prelog, Angew. Chem., Int. Ed. Engl., 1982, 21, 654.

Key Words:
C-C BOND FORMATION/APPENDAGES/ENANTIOGENIC REACTIONS/PHYSICAL ORGANIC/STEREOCHEMISTRY



Self-regeneration of stereocenters (SRS) - Applications, limitations, and abandonment of a synthetic principle.

D. Seebach, A. R. Sting, M. Hoffmann, Angew. Chem., Int. Ed. Engl., 1996, 35, 2708.

Key Words:
ASYMMETRIC SYNTHESES/CHIRAL SYNTHETIC BUILDING BLOCKS/ENOLATES LITHIUM COMPOUNDS/ALPHA-AMINO-ACIDS/DIELS-ALDER REACTIONS/CHIRAL BUILDING-BLOCKS/ENANTIOMERICALLY PURE DIHYDROPYRIMIDINONES/RAY CRYSTAL-STRUCTURE/EFFICIENT ENANTIOSELECTIVE SYNTHESIS/DIASTEREOSELECTIVE RADICAL-ADDITION/HETEROSUBSTITUTED CARBOXYLIC-ACIDS/STEREOSELECTIVE ALDOL REACTIONS/PIVALALDEHYDE N,N-ACETAL CENTER



D. Seebach, B. Weidmann, L. Widler, in Modern Synthetic Methods, Vol. 3 (Ed.: R. Scheffold), Springer, Berlin, 1983, p. 217.

Key Words:
ORGANOMETALLICS/TITANIUM/ZIRCONIUM/Ti/Zr