Chemistry of N-methoxy-N-methylamides. Applications in synthesis.

M. P. Sibi, Org. Prep. Proced. Int., 1993, 25, 15.

Key Words:



Are two phenyls better than one? Synthesis and applications of (R)-4-diphenylmethyl-2-oxazolidinone.

M. P. Sibi, Aldrichimica Acta, 1999, 32, 93.

Key Words:
FREE-RADICAL REACTIONS/ALPHA-AMINO-ACIDS/ASYMMETRIC-SYNTHESIS/ENANTIOSELECTIVE SYNTHESIS/(-)-ROCCELLARIC ACID/CHIRAL SYNTHESIS/STEREOSELECTIVE SYNTHESIS/ACYCLIC STEREOCONTROL/N-ENOYLOXAZOLIDINONES/GAMMA-BUTYROLACTONES



M. P. Sibi, J. Ji, in Progress in Heterocyclic Chemistry, Vol. 8 (Eds.: H. Suschitzky, G. W. Gribble), Pergamon, Oxford, U.K, 1996.

Key Words:



Stereoselective Conjugate Additions to Enoates.

M. P. Sibi, M. Liu, Enantiomer, 1999, 4, 575.

Key Words:
Enoates/stereoselective conjugate addition Enoates/amide addition



Reversal of stereochemistry in enantioselective transformations. Can they be planned or are they just accidental?.

M. P. Sibi, M. Liu, Curr. Org. Chem., 2001, 5, 719.

Key Words:
DIELS-ALDER REACTIONS; CHIRAL LEWIS-ACIDS; ASYMMETRIC CONJUGATE ADDITION; C-2-SYMMETRICAL COPPER(II) COMPLEXES; 1,3-DIPOLAR CYCLOADDITION REACTIONS; CATALYZED ALLYLIC ALKYLATION; TRANSITION-METAL COMPLEXES; FREE-RADICAL REACTIONS; ALPHA-IMINO ESTERS; ALDOL ADDITIONS



Enantioselective conjugate additions.

M. P. Sibi, S. Manyem, Tetrahedron, 2000, 56, 8033.

Key Words:
CATALYTIC ASYMMETRIC-SYNTHESIS/ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS/CHIRAL AMIDOPHOSPHINE LIGAND/BAYLIS-HILLMAN REACTION/ALPHA-CYANO CARBOXYLATES/FREE-RADICAL REACTIONS/AMINO ACID PRECURSORS/MICHAEL ADDITION/GRIGNARD-REAGENTS/PHOSPHORUS LIGANDS



Enantioselective free radical reactions.

M. P. Sibi, N. A. Porter, Acc. Chem. Res., 1999, 32, 163.

Key Words:
HYDROGEN-ATOM ABSTRACTION/CHIRAL LEWIS-ACID/ALPHA-SULFINYL RADICALS/BOND-FORMING REACTIONS/DIELS-ALDER REACTION/BETA-ALKOXY ESTERS/STEREOSELECTIVE REDUCTION/N-ENOYLOXAZOLIDINONES/ACYCLIC STEREOCONTROL/TIN HYDRIDE