Amino acids and their derivatives as stoichiometric auxiliaries in asymmetric synthesis.

A. Studer, Synthesis, 1996, 793.

Key Words:
DIELS-ALDER REACTIONS/CHROMIUM CARBENE COMPLEXES/ALPHA-KETO-AMIDES/CHIRAL LITHIUM AMIDES/ENANTIOSELECTIVE ALDOL REACTIONS/QUATERNARY CARBON CENTERS/ALDEHYDE-SAMP HYDRAZONES/DIPOLE-STABILIZED ANIONS/C-2 SYMMETRICAL AMINES/ACTIVE BETA-LACTAMS



The persistent radical effect in organic synthesis.

A. Studer, Chem. Eur. J., 2001, 7, 1159.

Key Words:
C-C coupling; homogeneous catalysis; persistent radical effect; radicals; synthetic methods; BOND-FORMING REACTIONS; RATE ENHANCEMENT; POLYMERIZATION PROCESS; UNUSUAL SELECTIVITIES; ADDITION REACTIONS; N-ALKOXYAMINES; GAMMA-LACTAMS; ALKYL; CYCLIZATION; COMPLEXES



Tin hydride substitutes in reductive radical chain reactions

A. Studer, S. Amrein, Synthesis, 2002, 835.

Key Words:
defunctionalizations/reductions/radical reactions/silicon/tin/ELECTRON-SPIN RESONANCE/CARBON BOND FORMATION/BARTON-MCCOMBIE DEOXYGENATION/POLARITY-REVERSAL CATALYSTS/ATOM ABSTRACTION REACTIONS/HYDROGEN DONOR ABILITIES/NORMAL-BUTYLTIN HYDRIDE/ORGANIC-SYNTHESIS/RATE CONSTANTS/CYCLIZATION REACTIONS



Radical aryl migration reactions.

A. Studer, M. Bossart, Tetrahedron, 2001, 57, 9649.

Key Words:
NEOPHYL-LIKE REARRANGEMENT; ELECTRON-SPIN-RESONANCE; IPSO SUBSTITUTION-REACTIONS; ABSOLUTE RATE CONSTANTS; HYDROGEN ABSTRACTION; ALKOXYL RADICALS; MODEL COMPOUNDS; RING EXPANSION; CARBON; CYCLIZATION



Fluorous Synthesis: A Fluorous-Phase Strategy for Improving Separation Efficiency in Organic Synthesis.

A. Studer, S. Hadida, R. Ferritto, S.-Y. Kim, P. Jeger, P. Wipf, D. P. Curran, Science, 1997, 275(5301), 823.

Key Words: