Sulfuranes in Organic Reactions and Synthesis.

B. M. Trost, Top. Curr. Chem., 1973, 41, 1.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ORGANOSULPHUR COMPOUNDS/SULFURANES/S



Organopalladium Intermediates in Organic Synthesis.

B. M. Trost, Tetrahedron, 1977, 33, 2615.

Key Words:
ORGANOMETALLICS/PALLADIUM/Pd



Alpha-Sulphenylated Carbonyl Compounds in Organic Synthesis.

B. M. Trost, Chem. Rev., 1978, 78, 363.

Key Words:
FUNCTIONAL GROUPS/PREPARATIONS/ORGANOSULPHUR COMPOUNDS/O=C-C-X/S/SULPHENYLATION/ALKYLATION/ENONES



Transition-Metal Templates for Selectivity in Organic Synthesis.

B. M. Trost, Aldrichimica Acta, 1981, 14, 43.

Key Words:



Cyclopentanoids: A Challenge for New Methodology.

B. M. Trost, Chem. Soc. Rev., 1982, 11, 141.

Key Words:
C-C BOND FORMATION/ANNULATIONS/5-RING



[3+2] Cycloaddition Approaches to Five-Membered Rings via Trimethylenemethane and its Equivalents.

B. M. Trost, Angew. Chem., Int. Ed. Engl., 1986, 25, 1.

Key Words:
C-C BOND FORMATION/PERICYCLIC REACTIONS/CYCLOADDITIONS/[3+2]/C=C-C-M/Si/ALKYLIDENECYCLOPROPANES/CARBRING/3/METHYLENECYCLOPENTENES CARBRING/5



Transition metals and olefins. A promising land: a personal account.

B. M. Trost, J. Organomet. Chem., 1986, 300, 263.

Key Words:
ORGANOMETALLICS/ORGANIC SYNTHESIS/PALLADIUM/TM/Pd/Mo/W



Transition metal templates as catalysts for selective organic transformations.

B. M. Trost, Chemtracts: Organic Chemistry, 1988, 1, 415.

Key Words:
ORGANOMETALLICS/PALLADIUM/COUPLING/Pd



Transition metal templates as guides for cycloadditions.

B. M. Trost, Pure Appl. Chem., 1988, 60, 1615.

Key Words:



Cyclizations via palladium-catalyzed allylic alkylation.

B. M. Trost, Angew. Chem., Int. Ed. Engl., 1989, 28, 1173.

Key Words:
Pd



Palladium-catalyzed cycloisomerization of enynes and related reactions.

B. M. Trost, Acc. Chem. Res., 1990, 23, 34.

Key Words:
ORGANOMETALLICS/PALLADIUM/C-C BOND FORMATION/ANNULATIONS/5-RING/6-RING/ANNULATION/5-RING,6-RING/C=C-C=C/Pd



The atom economy: a search for synthetic efficiency.

B. M. Trost, Science, 1991, 254, 1471.

Key Words:



B. M. Trost, in Studies in Natural Products Chemistry, Vol.8: Stereoselective Synthesis, Part E (Ed.: Atta-ur-Rahman), Elsevier, Amsterdam, Netherlands, 1991, pp. 277.

Key Words:



A biological catalysis for synthetic efficiency.

B. M. Trost, Pure Appl. Chem., 1992, 64, 316.

Key Words:



Enhanced Synthetic Efficiency towards Natural-Products via Transition-Metal-Catalyzed Reactions.

B. M. Trost, Pure Appl. Chem., 1994, 66, 2007.

Key Words:
TM



Atom economy - A challenge for organic synthesis: Homogeneous catalysis leads the way.

B. M. Trost, Angew. Chem., Int. Ed. Engl., 1995, 34, 259.

Key Words:
CARBON-CARBON COUPLING/CATALYSIS/CYCLOADDITIONS/SYNTHETIC METHODS/DIELS-ALDER REACTION/GOLD(I)-CATALYZED ALDOL REACTION/MEDIATED ENE CARBOCYCLIZATIONS/TRANSITION-METAL-COMPLEXES/ASYMMETRIC-SYNTHESIS/ALLYL ALCOHOLS/STEREOSELECTIVE SYNTHESIS/RECONSTITUTIVE CONDENSATION/CYCLO-ISOMERIZATION/INTRAMOLECULAR/Au



B. M. Trost, Springer, Berlin, Germany, 1995.

Key Words:



Designing a receptor for molecular recognition in a catalytic synthetic reaction: Allylic Alkylation.

B. M. Trost, Acc. Chem. Res., 1996, 29, 355.

Key Words:
CHIRAL PHOSPHINE-LIGANDS/ASYMMETRIC INDUCTION/ENANTIOSELECTIVE SYNTHESIS/SUBSTITUTION-REACTIONS/BUILDING-BLOCK/PALLADIUM/COMPLEXES/STEREOCHEMISTRY/MECHANISM/ACETATES



Molecular gymnastics of alkynes orchestrated by ruthenium complexes.

B. M. Trost, Chem. Ber., 1996, 129, 1313.

Key Words:
VINYLIDENE COMPLEXES/ALLENYLIDENE COMPLEXES/ENE TYPE REACTIONS/ATOM ECONOMICAL REACTIONS/RECONSTITUTIVE ADDITIONS/CATALYZED RECONSTITUTIVE CONDENSATION/CYCLOPENTADIENYL-OSMIUM CHEMISTRY/TRANSITION-METAL/ALLYL ALCOHOLS/TERMINAL ALKYNES/ORGANOMETALLIC CHEMISTRY/VINYLIDENE COMPLEXES/REDOX ISOMERIZATION/PROPARGYL ALCOHOLS/ATOM ECONOMY



Asymmetric introduction of heteroatoms.

B. M. Trost, Pure Appl. Chem., 1996, 68, 779.

Key Words:



When is a proton not a proton?.

B. M. Trost, Chem. Eur. J., 1998, 4, 2405.

Key Words:
catalysis/cyclizations/palladium protonations/transition metals/PALLADIUM-CATALYZED ADDITION/ASYMMETRIC-SYNTHESIS/HYDRIDE COMPLEXES/GENERAL STRATEGY/ALLENES/CYCLOISOMERIZATIONS/ISOMERIZATION/CYCLIZATION/1,3-DIENES/PRONUCLEOPHILES



Transition metal catalyzed cycloisomerizations.

B. M. Trost, M. J. Krische, Synlett, 1998, 1.

Key Words:
cycloisomerization/transition metal catalysis/macrocyclization/cyclization and atom economy/MEDIATED TETRAENE CARBOCYCLIZATIONS/INTRAMOLECULAR ENYNE METATHESIS/CHIRAL TITANIUM PERCHLORATE/CARBONYL-ENE CYCLIZATION/TO-TAIL DIMERIZATION/C-BOND FORMATION/ORGANIC-SYNTHESIS/ASYMMETRIC CATALYSIS/ATOM ECONOMY/ALPHA,ALPHA-DICHLORO ESTERS



Sulfones: Substitution by C-Nucleophiles.

B. M. Trost, C. A. Merlic, J. Am. Chem. Soc., 1988, 110, 5216.

Key Words:
C-C BOND FORMATION/APPENDAGES/ALKYLATION/FUNCTIONAL GROUPS/PREPARATIONS/ORGANOSULPHUR COMPOUNDS/C=C-C-X/SO2/SULPHONES/SUBSTITUTION/SO2 BY C/LEWIS ACID CATALYSIS/NUCLEOPHILIC DISPLACEMENT/S



Non-metathesis ruthenium-catalyzed C-C bond formation.

B. M. Trost, F. D. Toste, A. B. Pinkerton, Chem. Rev., 2001, 101, 2067.

Key Words:
LOW-VALENT RUTHENIUM; CARBON-HYDROGEN BONDS; TO-TAIL DIMERIZATION; DIELS-ALDER REACTION; TRANSFER RADICAL POLYMERIZATION; CROSS-COUPLING REACTION; H BONDS; TERMINAL ALKYNES; LEWIS-ACID; COORDINATION SPHERE



Asymmetric transition metal-catalyzed allylic alkylations.

B. M. Trost, D. L. Vanvranken, Chem. Rev., 1996, 96, 395.

Key Words:
PI-ALLYLPALLADIUM COMPLEXES/NUCLEAR-MAGNETIC-RESONANCE/FERROCENYLPHOSPHINE-PALLADIUM COMPLEXES/CHIRAL PHOSPHINE-LIGANDS/X-RAY STRUCTURE/ENANTIOSELECTIVE CATALYSIS/NUCLEOPHILIC-ADDITION/MOLECULAR-STRUCTURE/REDUCTIVE CLEAVAGE/OXAZOLINE LIGANDS



B. M. Trost, T. R. Verhoeven, in Comprehensive Organometallic Chemistry, Vol. 8 (Eds.: G. Wilkinson, F. G. A. Stone, E. Abel), Pergamon, Oxford, 1982, p. 799.

Key Words:
ORGANOMETALLICS/PALLADIUM/Pd