Complete Retention of Z Geometry in Allylic Substitution Catalyzed by an Iridium Complex
Ryo Takeuchi* and Norihito Shiga
*Department of Environmental Science, Faculty of Science and Graduate School of Integrated Science, Yokohama City University, 22-2 Seto, Kanazawa-ku, Yokohama 236-0027, Japan,
Email: takeuchi
chem.aoyama.ac.jp
R. Takeuchi, N. Shiga, Org. Lett., 1999, 1, 265-267.
DOI: 10.1021/ol990033n
Abstract
The Z geometry of methyl (Z)-3-monosubstituted-2-alkenyl carbonate was completely retained in iridium complex-catalyzed allylic amination. Various (Z)-allylic amines were obtained in high selectivity by allylic amination of methyl (Z)-3-monosubstituted-2-alkenyl carbonate.
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Key Words
ID: J54-Y1999
