A Facile Route to Acyclic Substituted α,β-Unsaturated Aldehydes: The Allene Claisen Rearrangement
Philip J. Parsons*, Peter Thomson, Andrew Taylor and Timothy Sparks
*The Chemical Laboratories, CPES, The University of Sussex, Falmer, Brighton BN1 9QJ, U.K.,
Email: p.parsons
imperial.ac.uk
P. J. Parsons, P. Thomson, A. Taylor, T. Sparks, Org. Lett., 2000, 2, 571-572.
DOI: 10.1021/ol990305m
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Abstract
Sigmatropic rearrangement of allenyl ethers furnishes α,β-unsaturated aldehydes in good yield.
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Key Words
Claisen rearrangement, 1,4-dienes
ID: J54-Y2000
