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N-(tert-Butoxycarbonyl)-N-[4-(dimethylazaniumylidene)-1,4-dihydropyridin-1-ylsulfonyl]azanide: A New Sulfamoylating Agent. Structure and Reactivity toward Amines

Jean-Yves Winum, Loic Toupet, Véronique Barragan, Georges Dewynter and Jean-Louis Montero*

*LCBM, UMR 5032, Universite Montpellier II, ENSCM, 8 Rue de l'Ecole Normale, 34296 Montpellier Cedex, France

J.-Y. Winum, L. Toupet, V. Barragan, G. Dewynter, J.-L. Montero, Org. Lett., 2001, 3, 2241-2243.

DOI: 10.1021/ol0161312 (free Supporting Information)


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Abstract

N-(tert-Butoxycarbonyl)-N-[4-(dimethylazaniumylidene)-1,4-dihydropyridin-1-ylsulfonyl]azanide allowed sulfamoylation of amines under very mild conditions to give sulfamide derivatives in good yields.

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Key Words

sulfamides


ID: J54-Y2001