Palladium-Catalyzed Cross-Coupling Reactions of in Situ Generated Allylindium Reagents with Aryl Halides

Phil Ho Lee*, Sun-young Sung and Kooyeon Lee

*Department of Chemistry, Kangwon National University, Chunchon 200-701, Republic of Korea, Email: phleekangwon.ac.kr

P. H. Lee, S.-y. Sung, K. Lee, Org. Lett., 2001, 3, 3201-3204.

DOI: 10.1021/ol016532h

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Abstract

In situ generated allylindium reagents could be effectively cross-coupled with aryl halides. The best results were obtained with catalytic amounts of Pd₂dba₃CHCl₃ and Ph₃P in the presence of 3 equiv of LiCl in DMF at 100 °C.

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Key Words

allylation of arenes

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ID: J54-Y2001