A Novel Use of Grubbs' Carbene. Application to the Catalytic Deprotection of Tertiary Allylamines
Benito Alcaide*, Pedro Almendros, Jose M. Alonso and Moustafa F. Aly
*Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040-Madrid, Spain
B. Alcaide, P. Almendros, J. M. Alonso, M. F. Aly, Org. Lett., 2001, 3, 3781-3784.
DOI: 10.1021/ol0167412
Abstract
Grubbs' carbene catalyzes a deprotection of allylic amines via a nitrogen-assisted ruthenium-catalyzed isomerization, followed by hydrolysis of the enamine intermediate.
see article for more examples
Key Words
ID: J54-Y2001