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A Novel Use of Grubbs' Carbene. Application to the Catalytic Deprotection of Tertiary Allylamines

Benito Alcaide*, Pedro Almendros, Jose M. Alonso and Moustafa F. Aly

*Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040-Madrid, Spain

B. Alcaide, P. Almendros, J. M. Alonso, M. F. Aly, Org. Lett., 2001, 3, 3781-3784.

DOI: 10.1021/ol0167412


Abstract

Grubbs' carbene catalyzes a deprotection of allylic amines via a nitrogen-assisted ruthenium-catalyzed isomerization, followed by hydrolysis of the enamine intermediate.

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Key Words

deallylation


ID: J54-Y2001