Stille Couplings Catalytic in Tin:  A "Sn-F" Approach

Robert E. Maleczka and William P. Gallagher

*Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, Email: maleczkachemistry.msu.edu

R. E. Maleczka, W. P. Gallagher, Org. Lett., 2001, 3, 4173-4176.

DOI: 10.1021/ol016792z

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Abstract

PMHS activated by KF allows Me₃SnH to be efficiently recycled during a Pd(0)-catalyzed hydrostannation/Stille cascade. This protocol offers short reaction times and proceeds through Me₃SnF intermediate.

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Key Words

Stille coupling, 1,3-Dienes, PMHS

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ID: J54-Y2001