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Efficient Synthesis of Cyclopentadienone Derivatives by the Reaction of Carbon Dioxide with 1,4-Dilithio-1,3-dienes

Zhenfeng Xi and Qiuling Song

*Department of Chemistry, Peking University, Beijing 100871, China, Email: zfxipku.edu.cn

Z. Xi, Q. Song, J. Org. Chem., 2000, 65, 9157-9159.

DOI: 10.1021/jo005641r


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Abstract

A one-pot reaction of carbon dioxide with 1,4-dilithio-1,3-diene derivatives affords cyclopentadienone derivatives bearing various substituents in high yields within minutes.

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Key Words

Cyclopentadienones


ID: J42-Y2000