Trifluoromethanesulfonyl Azide: A Powerful Reagent for the Preparation of α-Nitro-α-diazocarbonyl Derivatives
André B. Charette*, Ryan P. Wurz and Thierry Ollevier
*Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal (Québec) Canada, H3C 3J7,
Email: andre.charette
umontreal.ca
A. B. Charette, R. P. Wurz, T. Ollevier, J. Org. Chem., 2000, 65, 9252-9254.
DOI: 10.1021/jo001235w
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Abstract
The reaction of triflyl azide with α-nitrocarbonyl compounds in the presence of pyridine enables a highly efficient preparation of α-nitro-α-diazocarbonyl derivatives.
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Key Words
ID: J42-Y2000
