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Palladium-Catalyzed Intramolecular Addition of 1,3-Diones to Unactivated Olefins

Tao Pei and Ross A. Widenhoefer*

*Duke University, P. M. Gross Chemical Laboratory, Durham, North Carolina 27708-0346, Email: ross.widenhoeferduke.edu

T. Pei, R. A. Widenhoefer, J. Am. Chem. Soc., 2001, 123, 11290-11291.

DOI: 10.1021/ja011764x


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Abstract

A Pd(II)-catalyzed intramolecular addition of 1,3-diones to unactivated olefins provides cyclohexanones.

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Palladium-Catalyzed Intramolecular Oxidative Alkylation of Unactivated Olefins

T. Pei, X. Wang, R. A. Widenhoefer, J. Am. Chem. Soc., 2003, 125, 648-649.


Key Words

cyclohexanones


ID: J48-Y2001