The Chemistry of Alkylstrontium Halide Analogues, Part 2: Barbier-Type Dialkylation of Esters with Alkyl Halides
Norikazu Miyoshi *, Tsuyoshi Matsuo, Makoto Wada
*Department of Chemistry, Faculty of Integrated Arts and Sciences, The
University of Tokushima, 1-1 Minamijosanjima, Tokushima 770-8502, Japan, Email:
miyoshi
ias.tokushima-u.ac.jp
N. Miyoshi, T. Matsuo, M. Wada, Eur. J. Org. Chem., 2005, 4253-4255.
Abstract
Barbier-type alkylation of esters with alkyl iodides proceeded smoothly at room temperature in the presence of metallic strontium under argon to afford the corresponding dialkylated alcohols in good yields.
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Key Words
Strontium, Alcohols, Barbier-type reaction, Ester
ID: J24-Y2005-1730
