Palladium-Catalyzed Conversion of Benzylic and Allylic Halides into α-Aryl and β,γ-Unsaturated Tertiary Amides by the Use of a Carbamoylsilane
Robert F. Cunico* and Rajesh K. Pandey
*Department of Chemistry and Biochemistry, Northern Illinois University,
DeKalb, Illinois 60115, Email: rfc
marilyn.chem.niu.edu
R. F. Cunico, R. K. Pandey, J. Org. Chem., 2005, 70, 9048-9050.
DOI: 10.1021/jo0512406
Abstract
The palladium-catalyzed cross-coupling of allylic and benzylic halides with N,N-dimethylcarbamoyl(trimethyl)silane affords tertiary amides in good to excellent yields.
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Key Words
ID: J42-Y2005-1810
