α-Nitro Ketone Synthesis Using N-Acylbenzotriazoles
Alan R. Katritzky,* Ashraf A. A. Abdel-Fattah, Anna V. Gromova, Rachel Witek and Peter J. Steel
*Center for Heterocyclic Compounds, Department of Chemistry, University of
Florida, Gainesville, Florida 32611-7200, Email: katritzky
chem.ufl.edu
A. R. Katritzky, A. A. A. Abdel-Fattah, A. V. Gromova, R. Witek, P. J. Steel, J. Org. Chem., 2005, 70, 9211-9214.
DOI: 10.1021/jo051231x
Abstract
The conversion of primary nitroalkanes into the corresponding α-nitro ketones readily proceeds using N-acylbenzotriazoles as acylation agents.
see article for more examples
Efficient Conversion of Carboxylic Acids into N-Acylbenzotriazoles
A. R. Katritzky, N. Kirichenko, B. V. Rogovoy, Synthesis, 2003, 2777-2780.
Key Words
ID: J42-Y2005-1890
