Stereospecific Addition of H-P Bond to Alkenes: A Simple Method for the Preparation of (RP)-Phenylphosphinates
Li-Biao Han* and Chang-Qiu Zhao
*National Institute of Advanced Industrial Science and Technology (AIST),
Tsukuba, Ibaraki 305-8565, Japan, Email: libiao-han
aist.go.jp
L.-B. Han, C.-Q. Zhao, J. Org. Chem., 2005, 70, 10121-10123.
DOI: 10.1021/jo051582b
Abstract
A stereospecific radical or base-catalyzed addition of the easily available (-)menthyl phenylphosphinate to alkenes gave various optically pure alkylphenylphosphinates.
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Key Words
Radical Addition, Phosphinates
ID: J42-Y2005-2000
