Synthesis of Functionalized Benzylsilanes from Arylzinc Compounds and (Iodomethyl)trimethylsilane by Means of a Novel Rh Catalysis
Hideki Takahashi, Kabir M. Hossain, Yasushi Nishihara, Takanori Shibata and Kentaro Takagi*
*Department of Chemistry, Faculty of Science, Okayama University, Tsushima, Okayama 700-8530, Japan, takagicc.okayama-u.ac.jp
H. Takahashi, K. M. Hossain, Y. Nishihara, T. Shibata, K. Takagi, J. Org. Chem., 2006, 71, 671-675.
DOI: 10.1021/jo0520994
Abstract
The Rh-catalyzed cross-coupling between ArZnI and TMSCH2I gave various functionalized benzylsilanes in good yields. A mechanism is proposed.
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ID: J42-Y2006-120