Organomediated Morita-Baylis-Hillman Cyclization Reactions
Marie E. Krafft* and Thomas F. N. Haxell
*Department of Chemistry and Biochemistry, Florida State University,
Tallahassee, Florida 32306, Email: mek
chem.fsu.edu
M. E. Krafft, T. F. N. Haxell, J. Am. Chem. Soc., 2005, 127, 10168-10169.
DOI: 10.1021/ja052146+
Abstract
An organomediated, intramolecular Morita-Baylis-Hillman reaction of molecules bearing allylic leaving groups as the electrophilic partner provided a facile, high yielding, straightforward synthesis of densely functionalized cyclic molecules.
see article for more examples
Organocatalysis of the Morita-Baylis-Hillman Alkylation Using Trialkylphosphines
M. E. Krafft, K. A. Seibert, Synlett, 2006, 3334-3336.
Key Words
Baylis-Hillman Reaction, Organocatalysis, Cyclopentenes, Cyclohexenes, Enones
ID: J48-Y2005-2460
