Palladium-Catalyzed Cross-Coupling Reaction of Triorganoindium Reagents with Propargylic Esters
Ricardo Riveiros, David Rodríguez, José Pérez Sestelo and Luis A. Sarandeses*
*Departamento de Química Fundamental, Universidade da Coruña, E-15071 A
Coruña, Spain, Email: qfsarand
udc.es
R. Riveiros, D. Rodríguez, J. P. Sestelo, L. A. Sarandeses, Org. Lett., 2006, 8, 1403-1406.
DOI: 10.1021/ol060192o
Abstract
The palladium-catalyzed of triorganoindium reagents to propargylic esters afforded via an SN2' rearrangement allenes in good yields and with high regioselectivity. The reaction of chiral, nonracemic propargylic esters takes place with high anti-stereoselectivity providing allenes with high enantiomeric excess.
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Key Words
ID: J54-Y2006-800
