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Brønsted Acid Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyl Compounds to Alkenes and Alcohols

Ken Motokura, Noriaki Fujita, Kohsuke Mori, Tomoo Mizugaki, Kohki Ebitani, Kiyotomi Kaneda*

*Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Email: kanedacheng.es.osaka-u.ac.jp

K. Motokura, N. Fujita, K. Mori, T. Mizugaki, K. Ebitani, K. Kaneda, Angew. Chem. Int. Ed., 2006, 45, 2605-2609.

DOI: 10.1002/anie.200504609 (free Supporting Information)


Abstract

Environmentally benign additions of various 1,3-dicarbonyl compounds to alkenes and alcohols in the presence of solid acid catalysts have been described.

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Key Words

active methylenes


ID: J06-Y2006-950