Gold(I)-Catalyzed Intra- and Intermolecular Hydroamination of Unactivated Olefins

Junliang Zhang, Cai-Guang Yang and Chuan He*

*Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, Email: chuanheuchicago.edu

J. Zhang, C.-G. Yang, C. He, J. Am. Chem. Soc., 2006, 128, 1798-1799.

DOI: 10.1021/ja053864z

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Abstract

Ph₃PAuOTf catalyzes efficient intra- and intermolecular hydroamination of unactivated olefins with sulfonamides.

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Key Words

protected primary amines, sulfonamides, pyrrolidines

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ID: J48-Y2006-1580