A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols
Manuel A. Fernández-Rodríguez, Qilong Shen and John F. Hartwig*
*Department of Chemistry, Yale University, PO Box 208107 New Haven,
Connecticut 06520-8107, Email: john.hartwigyale.edu
M. A. Fernández-Rodríguez, Q. Shen, J. F. Hartwig, J. Am. Chem. Soc., 2006, 128, 2180-2181.
DOI: 10.1021/ja0580340
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Abstract
A general palladium-catalyzed reaction using the CyPF-t-Bu ligand for the coupling of aryl halides and sulfonates with thiols exhibits extraordinary turnover numbers and high tolerance of functional groups.
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Key Words
ID: J48-Y2006-1610