Substituted Allyl Diphenylphosphine Oxides as Radical Allylating Agents
Gilles Ouvry, Béatrice Quiclet-Sire, Samir Z. Zard*
*Laboratoire de Synthèse Organique Associé, CNRS (UMR 7652), Département de
Chimie, Ecole Polytechnique, 91128 Palaiseau Cedex, France, Email: zard
poly.polytechnique.fr
G. Ouvry, B. Quiclet-Sire, S. Z. Zard, Angew. Chem. Int. Ed., 2006, 45, 5002-5006.
DOI: 10.1002/anie.200601556
Abstract
A promising new approach to a generalized allylation process uses various easily accessible allyl diphenylphosphine oxides as radical trapping agents for the allylation of ditihocarbonates.
see article for more reactions and examples
Key Words
β-elimination, allylation, dithiocarbonates, phosphane oxides, radical reactions
ID: J06-Y2006-2190
